| 直接甲醇燃料电池用磺化聚醚醚酮质子交换膜 |
| |
| 引用本文： | 宋会平,郭强,许乐波.直接甲醇燃料电池用磺化聚醚醚酮质子交换膜[J].材料科学与工艺,2008,16(3):362-365,369. |
| |
| 作者姓名： | 宋会平 郭强 许乐波 |
| |
| 作者单位： | 上海大学,材料科学与工程学院,上海,201800 |
| |
| 摘 要： | 在回顾近年来直接甲醇燃料电池用磺化聚醚醚酮(SPEEK)质子交换膜的发展历程基础上,分别综述了制膜材料SPEEK的合成和SPEEK质子交换膜的制备研究进展,重点总结了SPEEK质子交换膜的电导率和阻醇性能及其稳定性的影响因素和影响规律,其中包括制膜材料和溶剂以及工艺、SPEEK的共混改性、SPEEK的填充改性或多层复合结构的影响,进而分析了高性能SPEEK质子交换膜的开发研究前景.
|
| 关 键 词： | 直接甲醇燃料电池 磺化聚醚醚酮 质子交换膜 电导率 阻醇性能 |
Proton exchange membranes made of sulfonated polyetheretherketone for direct methanol fuel cell |
| |
| SONG Hui-ping,GUO Qiang,XU Le-bo.Proton exchange membranes made of sulfonated polyetheretherketone for direct methanol fuel cell[J].Materials Science and Technology,2008,16(3):362-365,369. |
| |
| Authors: | SONG Hui-ping GUO Qiang XU Le-bo |
| |
| Affiliation: | (School of Materials Science and Engineering,Shanghai University,Shanghai 201800,China) |
| |
| Abstract: | On the basis of the retrospect on the development of the proton exchange membranes(PEM) made of sulfonated polyetheretherketone(SPEEK) used in the direct methanol fuel cell(DMF),the study progresses of the synthesis method of SPEEK,the sulfonation of polyetheretherketone(PEEK) for making SPEEK and the preparation technique of SPEEK proton exchange membranes are reviewed respectively.Effects of the SPEEK resin sulfonation degree,solvent for the membrane preparation,preparation process,SPEEK blend resin,filled SPEEK material and multilayer composite membrane structure on the properties of SPEEK proton exchange membranes,such as the conductivity,the methanol diffusion resistance and the stability,are summarized.In addition,some advance trends of the further research on SPEEK proton exchange membrane are analyzed and expected. |
| |
| Keywords: | direct methanol fuel cell sulfonated polyetheretherketone(SPEEK) proton exchange membrane conductivity methanol diffusion resistance |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
