| 聚合物协助燃烧法合成La0.8Sr0.2Co0.5Fe0.5O3-δ纳米粉体 |
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| 引用本文： | 陈静,刘丽娜,王方中,蒲健,池波,李箭.聚合物协助燃烧法合成La0.8Sr0.2Co0.5Fe0.5O3-δ纳米粉体[J].材料科学与工艺,2011,19(1):71-75,79. |
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| 作者姓名： | 陈静 刘丽娜 王方中 蒲健 池波 李箭 |
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| 作者单位： | 华中科技大学材料科学与工程学院材料成型与模具技术国家重点实验室;河南工业大学化学化工学院; |
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| 基金项目： | 国家自然科学基金资助项目(50571038); 武汉市晨光计划资助项目(200750731260) |
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| 摘 要： | 为开发新型高性能中温固体氧化物燃料电池阴极材料,以La、Sr、Co和Fe的硝酸盐、葡萄糖和丙烯酰胺为原料,在pH=8-10的碱性条件,通过聚合物协助燃烧法制备了La0.8 Sr0.2 Co0.5 Fe0.5 O3-δ(LSCF)钙钛矿相纳米粉体.用XRD、SEM和TEM表征了LSCF粉体的相结构和微观形貌,结果显示,在...
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| 关 键 词： | 固体氧化物燃料电池 LSCF 聚合物协助燃烧法 阴极 |
The preparation of La0.8Sr0.2Co0.5Fe0.5O3-δ nano-powders by a polymer-assisted synthesis method |
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| CHEN Jing,LIU Li-n,WANG Fang-zhong,PU Jian,CHI Bo and LI Jian.The preparation of La0.8Sr0.2Co0.5Fe0.5O3-δ nano-powders by a polymer-assisted synthesis method[J].Materials Science and Technology,2011,19(1):71-75,79. |
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| Authors: | CHEN Jing LIU Li-n WANG Fang-zhong PU Jian CHI Bo and LI Jian |
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| Affiliation: | CHEN Jing1,2,LIU Li-na1,WANG Fang-zhong1,PU Jian1,CHI Bo1,LI Jian1(1.School of Materials Science and Engineering,State Key Laboratory of Materials Processing and Die & Mould Technology,Huazhong University of Science and Technology,Wuhan 430074,China,2.Chemistry and Chemical Engineering School,Henan University of Technology,Zhengzhou 450001,China) |
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| Abstract: | To develop novel cathode materials with high performance for intermediate temperature solid oxide fuel cells(SOFC),La0.8Sr0.2Co0.5Fe0.5O3-δ(LSCF) nano-powders was synthesized by a polymer-assisted synthesis method using glucose and acrylamide with metal nitrates(La(NO3)3·6H2O,Sr(NO3)3,Co(NO3)3·6H2O,Fe(NO3)3·9H2O) as raw materials under the condition of pH=8~10.Then the as-prepared powders were characterized with XRD,SEM,and TEM.The effect of the ratio of glucose and acrylamide to metal nitrates on the particle size was investigated in detail.The results indicated that the particle size of LSCF decreased with the increasing ratio of glucose and acrylamide to metal nitrates.The polarization resistance is 0.72 Ω·cm2 and 0.11 Ω·cm2 at 700 and 750 ℃,respectively.The research reveals that the method used here is suitable to prepare high performance cathode material for SOFC. |
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| Keywords: | solid oxide fuel cells LSCF polymer-assisted combustion synthesis cathode |
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