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大气等离子体喷涂Sm2Zr2O7涂层的结构和性能
引用本文:于建华,赵华玉,周霞明,陶顺衍,丁传贤.大气等离子体喷涂Sm2Zr2O7涂层的结构和性能[J].无机材料学报,2011(7):696-700.
作者姓名:于建华  赵华玉  周霞明  陶顺衍  丁传贤
作者单位:中国科学院特种无机涂层重点实验室;中国科学院上海硅酸盐研究所;
摘    要:稀土锆酸盐材料具有比Y2O3部分稳定ZrO2陶瓷低的热导率,是新型热障涂层的潜在候选材料之一.利用大气等离子体喷涂技术以喷雾造粒的Sm2Zr2O7粉体制备涂层,并在相同条件下沉积8wt%Y2O3稳定ZrO2涂层.对比评价了两种涂层的结构、热物理性能和力学性能.X射线衍射结果表明,制备态Sm2Zr2O7涂层为缺陷萤石结构.扫描电镜分析显示,Sm2Zr2O7和8wt%Y2O3稳定ZrO2涂层为典型的层状结构,内部有很多气孔、裂纹等缺陷.800℃测得的Sm2Zr2O7涂层的热导率为0.44 W/(m.K),比相同条件下测得的8wt%Y2O3稳定ZrO2涂层的热导率低~40%,两者的热膨胀系数相似.力学测试结果显示,Sm2Zr2O7涂层的抗折强度、硬度和弹性模量均低于8wt%Y2O3稳定ZrO2涂层.

关 键 词:等离子体喷涂  Sm2Zr2O7涂层  热导率  力学性能

Microstructure and Properties of Air Plasma Sprayed Sm_2Zr_2O_7 Coatings
YU Jian-Hua,ZHAO Hua-Yu,ZHOU Xia-Ming,TAO Shun-Yan,DING Chuan-Xian.Microstructure and Properties of Air Plasma Sprayed Sm_2Zr_2O_7 Coatings[J].Journal of Inorganic Materials,2011(7):696-700.
Authors:YU Jian-Hua    ZHAO Hua-Yu  ZHOU Xia-Ming  TAO Shun-Yan  DING Chuan-Xian
Affiliation:YU Jian-Hua1,2,ZHAO Hua-Yu1,ZHOU Xia-Ming1,TAO Shun-Yan1,DING Chuan-Xian1,2(1.Key Laboratory of Inorganic Coating Materials,Chinese Academy of Sciences,Shanghai 200050,China,2.Shanghai Insti-tute of Ceramics,China)
Abstract:Rare-earth zirconates with a pyrochlore structure have attracted great attention for potential application in thermal barrier coating systems.In the present work,Sm2Zr2O7 coatings were deposited by atmospheric plasma spraying technology.Their microstructure,thermo-physical and mechanical properties were examined,and com-pared with that of 8wt% Y2O3 stabilized ZrO2 coatings which was deposited under the same plasma spraying condi-tions.X-ray diffraction result shows that the as-sprayed Sm2Zr2O7 coating exhib...
Keywords:plasma spraying  Sm2Zr2O7 coating  thermal conductivity  mechanical property  
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