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碲基复合材料薄膜的三阶非线性光学特性
引用本文:甘平,辜敏,李强,鲜晓东.碲基复合材料薄膜的三阶非线性光学特性[J].无机材料学报,2011,26(3):295-299.
作者姓名:甘平  辜敏  李强  鲜晓东
作者单位:重庆大学1. 西南资源开发及环境灾害控制工程教育部重点实验室; 2. 通信工程学院; 3. 自动化学院, 重庆 400044
基金项目:重庆市科委科技计划项目院士专项(CSTC,2008BC4003); 厦门大学表面物理化学国家重点实验室2007年度开放课题~~
摘    要:采用电化学诱导溶胶-凝胶法在导电玻璃片上制备了具有三阶非线性光学特性的碲基复合薄膜材料. 采用SEM( 扫描电镜)和EDX( X 光电子能谱)对薄膜的表面形貌和组成进行表征; 应用分光光度计得到薄膜的透射光谱、反射光谱、吸收光谱, 并结合脉冲激光器和 Z 扫描方法测量薄膜的三阶非线性光学特性. 实验结果表明制备的薄膜呈网状结构, 表面组分主要包括Si、Te、O元素; 薄膜在波长为1064nm处呈现负的非线性折射效应和饱和吸收的性质, 其非线性折射系数和非线性吸收系数分别为-4.18×10 - 13 m2/W和-1.6×10 - 6 m/W, 表明了碲基复合薄膜有较强的非线性光学效应, 得到三阶极化率为1.13×10 - 14 (m/V)2, 表明复合薄膜具有优良的三阶非线性光学性能.

关 键 词:碲基复合材料  薄膜  Z扫描法  三阶光学非线性  
收稿时间:2010-06-02
修稿时间:2010-09-08

Third-order Non-linear Optical Properties of Tellurium-based Composite Films
GAN Ping,GU Min,LI Qiang,XIAN Xiao-Dong.Third-order Non-linear Optical Properties of Tellurium-based Composite Films[J].Journal of Inorganic Materials,2011,26(3):295-299.
Authors:GAN Ping    GU Min  LI Qiang  XIAN Xiao-Dong
Affiliation:1. Key Laboratory for the Exploitation of Southwestern Resources and the Environmental Disaster Control Engineering, Ministry of Education, Chongqing University, Chongqing 400044, China; 2. College of Communication Engineering, Chongqing University, Chongqing 400044, China; 3. Collegeof Automation, Chongqing University, Chongqing 400044, China
Abstract:Tellurium-based composite films with third-order nonlinear optical properties were prepared by electrochemically induced Sol-Gel method using ITO glass as the substrate.The surface morphology and composition of the thin films were characterized by SEM(scanning electron microscope) and EDX(X-ray energy-dispersion spectroscope).The transmission spectrum,reflectance optical spectrum and absorption spectrum of the thin films were recorded on a spectrophotometer and the third-order optical nonlinearity of the fi...
Keywords:tellurium-based composite materials  thin films  Z-scan technology  third-order optical nonlinearities  
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