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磷酸盐晶体中络阴离子结晶方位与晶体形态
引用本文:仲维卓,罗豪,黄宣威,齐振一,华素坤.磷酸盐晶体中络阴离子结晶方位与晶体形态[J].无机材料学报,1999,14(2):223-227.
作者姓名:仲维卓  罗豪  黄宣威  齐振一  华素坤
作者单位:中国科学院上海硅酸盐研究所!上海,200050,中国科学院功能材料开放实验室!上海,200050
基金项目:国家自然科学基金!59872084
摘    要:研究了磷酸盐类晶体中的络阴离子PO4]-和CaP6O24]16-在晶体中的结晶方位,与ClCa6]11 八面体相互联结的稳定性决定了各个面族的生长速率.根据磷灰石各族晶面显露的习性,提出了采用人工生长的磷灰石做人工关节时,应该注意磷灰石的取向问题.平行于C轴方向生长的磷灰石有利于与人体骨骼的快速愈合.

关 键 词:晶体结构  结晶方位  磷酸盐  结晶形态  晶体
收稿时间:1998-4-27
修稿时间:1998-6-11

Crystallographic Orientation and Morphology of Anionic Coordination Phosphate Crystals
ZHONG Wei-zhuo,LUO Hao-su,HUANG Xuan-wei.Crystallographic Orientation and Morphology of Anionic Coordination Phosphate Crystals[J].Journal of Inorganic Materials,1999,14(2):223-227.
Authors:ZHONG Wei-zhuo  LUO Hao-su  HUANG Xuan-wei
Affiliation:LabofFunctionalInorganicMaterials;ChineseAcademyofSciencesShanghaiInstituteofCeramics;ChineseAcademyofSciencesShanghai200050China
Abstract:The growth rate of each face was determined by the crystallographic orientations of anionic coordinations such as PO4]3- and CaP6O24]16- in phosphate crystals and the stability of their combining with octahedral ClCa6]11 . According to the crystal habit of appearance for each face in phosphorite,the crystallographic orientation should be paid a great attention to the growth of phosphorite for its application on artificial joints.The Phosphorite grown in direction parallel with the c-axis will promote the recovery of bones in the human body.
Keywords:crystal structure  anionic coordination polygedron  crystallographic orientation  crystal habit
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