| 纳米Pd-Ga/PMMA复合体系界面的有序结构 |
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| 引用本文： | 徐国财,戴明虎,张晓梅,高圣涛,邢宏龙.纳米Pd-Ga/PMMA复合体系界面的有序结构[J].材料研究学报,2011(3):303-307. |
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| 作者姓名： | 徐国财 戴明虎 张晓梅 高圣涛 邢宏龙 |
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| 作者单位： | 安徽理工大学化学工程学院; |
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| 基金项目： | 安徽省自然科学基金090414183; 安徽省高校科研基金KJ2009A46资助项目~~ |
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| 摘 要： | 在不使用引发剂和还原剂条件下,用超声辐射工艺双原位合成了纳米钯镓/聚甲基丙烯酸甲酯(PMMA)复合物.XRD和UV-Vis显示,超声还原生成的单质钯和超声粉碎的单质镓在PMMA基体中不是简单的物理分散,而是在生成钯镓合金Ga5Pd/PMMA复合物的同时既有纳米钯又有纳米镓与PMMA形成复合物；XPS表明,镓失去了部分外...
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| 关 键 词： | 复合材料 纳米钯镓 聚甲基丙烯酸甲酯 超声 界面结构 纳米复合物 |
Interface Order-microstructure of Nano Pd-Ga Alloy/PMMA Composites |
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| XU Guocai DAI Minghu ZHANG Xiaomei GAO Shengtao XING Honglong.Interface Order-microstructure of Nano Pd-Ga Alloy/PMMA Composites[J].Chinese Journal of Materials Research,2011(3):303-307. |
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| Authors: | XU Guocai DAI Minghu ZHANG Xiaomei GAO Shengtao XING Honglong |
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| Affiliation: | XU Guocai~(**) DAI Minghu ZHANG Xiaomei GAO Shengtao XING Honglong (School of Chemical Engineering,Anhui University of Science and Technology,Huainan 232001) |
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| Abstract: | Nano Ga-Pd/poly methyl methacrylate（PMMA） composite materials were prepared with the palladium chloride solution containing metal gallium、MMA as monomer without initiator or reducer. Results show that there are Pd,Ga,and Ga5Pd phase in PMMA matrix.There was a characteristic absorption peak at 200 nm for nano-Ga/PMMA polymer solution,at 209 nm for nano-Pd/PMMA polymer solution,and the absorption peak of nano Pd-Ga/PMMA shiftted to long wavelength at 218 nm;Nano Ga5Pd formed based on segment electronics shifting from gallium to palladium,and coordination formed found on part electronics diverted from gallium to oxygen of PMMA ester group.PMMA possess anisotropic ordered microstructure around nano Ga-Pd particles,illustrating that there are interaction between nano Ga-Pd particles as dispersive and PMMA as continuous phase. |
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| Keywords: | composites nano Pd-Ga PMMA ultrasonic interface structure nanocomposite |
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