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ABS塑料电镀的高锰酸钾前处理工艺
引用本文:孙盾,何建平,周建华,杨少华,王涛,狄志勇,朱建龙,赵军,薛花娟.ABS塑料电镀的高锰酸钾前处理工艺[J].材料保护,2009,42(12).
作者姓名:孙盾  何建平  周建华  杨少华  王涛  狄志勇  朱建龙  赵军  薛花娟
作者单位:1. 南京航空航天大学材料科学与技术学院,江苏,南京,210016
2. 江苏法尔胜新日制铁缆索有限公司,江苏,江阴,214445
基金项目:国家自然科学基金项目,航空科学基金项目 
摘    要:传统的铬酸粗化对环境有污染.采用高锰酸钾代替铬酸粗化ABS塑料,在塑料基体上化学镀镍后电镀铜镍,讨论了粗化时间、温度和高锰酸钾浓度对化学镀镍层质量的影响,并以化学镀镍层的表面状态和结合力为评价标准,确定了高锰酸钾粗化的最佳工艺.结果表明:20 g/L高锰酸钾,粗化温度70℃,粗化时间40 min时的粗化效果最优;所得铜镍镀层光亮、均匀,达到GB/T 12610-90质量要求;高锰酸钾最佳粗化工艺下粗化效果良好,可满足生产要求,且对环境污染小,具有广阔的应用前景.

关 键 词:粗化  ABS塑料  高锰酸钾粗化液  无铬前处理  化学镀镍  电镀铜镍

Pretreatment for Electroplating of ABS Plastics by Potassium Hypermanganate
SUN Dun,HE Jian-ping,ZHOU Jian-hua,YANG Shao-hua,WANG Tao,DI Zhi-yong,ZHU Jian-long,ZHAO Jun,XUE Hna-juan.Pretreatment for Electroplating of ABS Plastics by Potassium Hypermanganate[J].Journal of Materials Protection,2009,42(12).
Authors:SUN Dun  HE Jian-ping  ZHOU Jian-hua  YANG Shao-hua  WANG Tao  DI Zhi-yong  ZHU Jian-long  ZHAO Jun  XUE Hna-juan
Affiliation:SUN Dun1,HE Jian-ping1,ZHOU Jian-hua1,YAHC Shao-hua1,WANG Tao1,DI Zhi-yong1,ZHU Jian-long2,ZHAO Jun2,XUE Hua-juan2(1.College of Material Science , Tech-nology,Nanjing University of Aeronautics , Astronautics,Nanjing 210016,China,2.Jiangsu Fasten-Nippon Steel Cable Co.,LTD,Jiangyin 214445,China)
Abstract:Potassium hypermanganate(KMnO4) was used as a replacement of H2CrO4 to conduct Cr-free roughening of acrylo-nitrile-butadiene-styrene(ABS) plastics.The resulting rough-ened ABS plastics were chemically plated with Ni,followed by Cu-Ni alloy electroplating.The effects of roughening time,tempera-ture,and concentration of KMnO4 on the quality of the electroless Ni coating were investigated.And the optimized roughening process of the ABS plastics by aqueous solution of KMnO4 was es-tablished in relation to the ...
Keywords:roughening  ABS plastics  potassium permanganate  Cr-free pretreatment  electroless Ni plating  Cu-Ni alloy electroplating
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