Crystalline perfection and optical properties of rapid grown KH2PO4 crystal with chromate additive |
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Authors: | JIANXU DING BING LIU SHENGLAI WANG XIAOMING MU SHENGJUN ZHU GUANGXIA LIU WENJIE LIU YUN SUN LIN LIU DUANLIANG WANG |
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Affiliation: | 1. State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, China 2. New Material Institute of Shandong Academy of Sciences, Jinan, 250014, China 3. No. 52 Institute of North Industries Group, Yantai Department, Yantai, 264003, China
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Abstract: | Potassium dihydrogen phosphate (KDP) crystals were grown in the presence of a series of chromate (CrO $_{4}^{2-}$ ) additive concentrations via rapid growth method. CrO $_{4}^{2-}$ made KDP crystals were coloured by yellow-green, suggesting CrO $_{4}^{2-}$ had entered into the crystal lattice. The elemental analysis indicated that Cr element in KDP crystal was at ppm level. High resolution X-ray diffraction data revealed that the crystalline perfection of these as-grown KDP crystals was destroyed after CrO $_{4}^{2-}$ entered into crystal lattice, embedded in the full width at half maximum was broadened and satellite peaks appeared. Additionally, the extinction ratio was decreased with rise of CrO $_{4}^{2-}$ concentration. CrO $_{4}^{2-}$ introduced two absorption peaks centred at 360 and 280 nm and enhanced the intrinsic absorption near 220 nm, which were at the same band positions compared with the CrO $_{4}^{2-}$ or HCrO $_{4}^{-}$ transmittance spectra. Additionally, CrO $_{4}^{2-}$ could increase the size of light scattering, which was attributed to the point defects and microscopic defects by the replacement by CrO $_{4}^{2-}$ at PO $_{4}^{3-}$ position. |
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