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SiO2不同的掺杂方式对聚氨酯树脂材料性能的影响
引用本文:张志华,沈军,吴广明,夏长生,杨帆,付甜,孙骐,王珏.SiO2不同的掺杂方式对聚氨酯树脂材料性能的影响[J].材料导报,2003,17(Z1):127-130.
作者姓名:张志华  沈军  吴广明  夏长生  杨帆  付甜  孙骐  王珏
作者单位:同济大学波耳固体物理研究所,上海,200092
基金项目:国家自然科学基金,上海市纳米科技专项基金,上海市学科建设项目,20133040,69978017,0152nm012,0159nm039,,,,
摘    要:采用溶胶凝胶法制备纳米SiO2颗粒,然后在聚氨酯弹性体/SiO2复合材料的不同制备方法方面进行了尝试,并针对SiO2不同的掺杂方式对聚氨酯树脂材料性能的影响进行了研究,为聚氨酯弹性体性能的优化提供了一条最佳的思路和方法.利用红外分光光度计(IR)、万能电子试验机、动态力学分析仪(DMA)、量热示差扫描仪(DSC)、紫外/可见/近红外分光光度计(UV/VIS/VIR)分别表征了纳米复合树脂材料的结构、力学性能、热稳定性、展色性和干爽性.

关 键 词:纳米SiO2颗粒  溶胶-凝胶  聚氨酯树脂  纳米复合材料  力学性能  热稳定性  展色性

Influence of Different Nano SiO2 Particle Doping Methods on Polyurethane Materials
ZHANG Zhihua SHEN Jun WU Guangming XIA Changsheng YANG Fan FU Tian SUN Qi WANG Jue.Influence of Different Nano SiO2 Particle Doping Methods on Polyurethane Materials[J].Materials Review,2003,17(Z1):127-130.
Authors:ZHANG Zhihua SHEN Jun WU Guangming XIA Changsheng YANG Fan FU Tian SUN Qi WANG Jue
Abstract:In order to obtain an optimized method for compounding, the influence of different nano SiO2 particle doping methods on polyurethane materials was investigated in this work. Nano SiO2 particles were prepared by sol-gel process, and polyurethane/SiO2 nano-composite materials were prepared by different nano-SiO2 particle doping methods. The chemical structure of nano-composites were characterized by infrared spectroscopy (IR) ,and the mechanical properties, thermal stability and color contrast properties of the polyurethane/SiO2 nano-composite materials were studied by universal electron tester, dynamic mechanical analyser (DMA),differential scanning calorimeter (DSC) and UV/VIS/VIR spectrophotometer.
Keywords:nano SiO2 particle  sol-gel  polyurethane resin  nano composite  mechanical property  heat-resistant  color contrast properties  anti adhesive properties
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