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从热蒸发多孔氧化硅薄膜表面形貌研究其生长机理
引用本文:赵丽特,范东华,朱慧群,罗坚义,王忆,龙拥兵,文铨.从热蒸发多孔氧化硅薄膜表面形貌研究其生长机理[J].材料导报,2015,29(12):37-42.
作者姓名:赵丽特  范东华  朱慧群  罗坚义  王忆  龙拥兵  文铨
作者单位:五邑大学应用物理与材料学院,江门,529020
基金项目:五邑大学青年基金,广东省教育厅科技创新项目,广东高校特色创新项目,江门市科技计划项目
摘    要:薄膜的表面形貌与生长机理相关,因此可以通过研究薄膜表面形貌的演变来外推其生长机理。利用热蒸发法在硅片上制备了纳米多孔二氧化硅薄膜,利用扫描电镜(SEM)和X射线能谱(EDS)对不同样品的形貌、成分进行了表征。研究发现所制备的薄膜是由线状结构或直立的片状结构所构成的多孔结构。利用马拉高尼效应和润湿理论,对薄膜的气-液-固生长机理和氧化物辅助生长机理进行了探讨。

关 键 词:薄膜  多孔氧化硅  纳米线  纳米片  生长机理

Study on Growth Mechanism from Morphology of Porous Silica Films Deposited by Thermal Evaporation
ZHAO Lite,FAN Donghu,ZHU Huiqun,LUO Jianyi,WANG Yi,LONG Yongbing and WEN Quan.Study on Growth Mechanism from Morphology of Porous Silica Films Deposited by Thermal Evaporation[J].Materials Review,2015,29(12):37-42.
Authors:ZHAO Lite  FAN Donghu  ZHU Huiqun  LUO Jianyi  WANG Yi  LONG Yongbing and WEN Quan
Affiliation:School of Applied Physics and Materials, Wuyi University, Jiangmen 529020,School of Applied Physics and Materials, Wuyi University, Jiangmen 529020,School of Applied Physics and Materials, Wuyi University, Jiangmen 529020,School of Applied Physics and Materials, Wuyi University, Jiangmen 529020,School of Applied Physics and Materials, Wuyi University, Jiangmen 529020,School of Applied Physics and Materials, Wuyi University, Jiangmen 529020 and School of Applied Physics and Materials, Wuyi University, Jiangmen 529020
Abstract:Because the surface morphology of the film is correlated with its growth mechanism, its growth mechanism can be deduced from the evolution of the surface morphology. Porous silica films were prepared on Si substrates by thermal evaporation deposition methods. The surface morphology and composition of different samples were described by means of scanning electron microscope and X-ray energy dispersive spectroscopy, whose results indicated the prepared samples have porous structure composed of nanowires or stand-up nanosheets. The growth mechanisms of films, including the vapor-liquid-solid mechanism and oxide-assisted growth mechanism,were also discussed by Marangoni effect and wetting theory.
Keywords:thin films  porous silica  nanowires  nanosheets  growth mechanism
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