新型纳米多孔材料——金属有机配位聚合物的包结作用及其应用研究进展

金属有机配位聚合物(MOCPs)具有纳米多孔的特殊结构,且结构具有可设计性,通过MOCPs活性位点与客体分子的包结作用能够选择性地包结多种客体分子,表现出特有的分子识别能力.MOCPs作为一种新型多孔材料在择形及手性催化、吸附分离、气体储存、分子识别与传感、生物模拟、微反应器等研究应用方面具有诱人的潜力.综述了MOCPs的设计、合成及主-客体相互作用方式,并展望了这种聚合物的应用前景.

Research Progress in the Inclusion Behavior and the Application of Metal-Organic Coordination Polymers

The metal-organic coordination polymers(MOCPs)possess special nano-porons and designed struc-tares.These materials exhibit the capacity of molecular recognition and can incluse a variety of guest molecules selec-tively by the special interaction of MOCPs'active point with guest molecular.As a novel nano-porous material,they have attractive potential applications at the shape-selective,chiral catalysis,adsorption separation,gas storage,mo-lecular recognition and sensing,biological simulation,micro-reactor and so on.The research progress in the design,synthesis and the interaction behavior in host-guest complex of MOCPs have been reviewed in this paper.In addition,the prospect of MOCPs is also presented.