Electrodeposition of nanocrystalline chromium-carbon alloys from electrolyte based on trivalent chromium sulfate using pulsed current |
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Authors: | F I Danilov V S Protsenko V O Gordiienko A S Baskevich V V Artemchuk |
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Affiliation: | 1.Ukrainian State University of Chemical Technology,Dnepropetrovsk,Ukraine;2.Dnipropetrovsk National University of Railway Transport named after Academician V. Lazaryan,Dnepropetrovsk,Ukraine |
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Abstract: | The effect of the parameters of pulsed electrolysis on the current efficiency, nanocrystal size, composition, hardness, friction
coefficient, and wear resistance of nanocrystalline Cr-C coatings obtained from electrolyte based on Cr(III) sulfate containing
carbamide and formic acid is studied. It is shown that coatings contain ∼9 wt % of carbon; the current density and pulse ratio
produce practically no effect on their composition. It is found that a maximum appears on the dependence of current efficiency
on pulse ratio in the case of the pulse ratio of ∼1.05–1.1. Thereby, current efficiency greatly exceeds the value implemented
in the steady-state current mode. It is shown that, if the microhardness of Cr-C deposits obtained at constant current is
close to 850–900 HV, the microhardness may increase to ∼1200−300 HV when pulsed electrolysis is used in certain modes. It
is found that application of pulsed electrolysis allows a significant decrease in the friction coefficient of chromium-carbon
coating (steel counterbody) both under the dry friction conditions and in the case of boundary lubrication and also results
in an increase in the deposit wear resistance. |
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