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Low-temperature sintering process for UO2 pellets in partially-oxidative atmosphere
作者姓名:杨晓东  高家诚  王勇  畅欣
作者单位:[1]College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China [2]Yibin Nuclear Fuel Element Plant, Yibin 644000, China
摘    要:Low-temperature sintering(LTS) experiments of UO2 pellets and their results were reported. Moreover, a routine process of LTS for UO2 pellets was primarily established. Being sintered at 1 400 ℃ for 3 h in a partially-oxidative atmosphere, the relative density of the pellet can be up to around 94%. Pellets with such a high density are of benefit for following-up reduction-sintering processes. Orthogonal test indicates that the importance of factors affecting the density decreases in the sequence of partial-oxidative sintering temperature and time, reduction-sintering time and temperature, and sintering atmosphere. It is found that it is helpful to introducing a small amount of water vapor into the sintering atmosphere during the latter stage. It is believed that it is the key factor to raise the O/U ratio of original powder in order to improve the properties of the low-temperature sintered pellets.

关 键 词:UO2颗粒  低温烧结  烧结温度  烧结时间
收稿时间:2007-01-17
修稿时间:2007-06-22

Low-temperature sintering process for UO2 pellets in partially-oxidative atmosphere
YANG Xiao-dong,GAO Jia-cheng,WANG Yong,CHANG Xin.Low-temperature sintering process for UO2 pellets in partially-oxidative atmosphere[J].Transactions of Nonferrous Metals Society of China,2008,18(1):171-177.
Authors:YANG Xiao-dong  GAO Jia-cheng  WANG Yong  CHANG Xin
Abstract:Low-temperature sintering(LTS) experiments of UO2 pellets and their results were reported. Moreover, a routine process of LTS for UO2 pellets was primarily established. Being sintered at 1 400 ℃ for 3 h in a partially-oxidative atmosphere, the relative density of the pellet can be up to around 94%. Pellets with such a high density are of benefit for following-up reduction-sintering processes. Orthogonal test indicates that the importance of factors affecting the density decreases in the sequence of partial-oxidative sintering temperature and time, reduction-sintering time and temperature, and sintering atmosphere. It is found that it is helpful to introducing a small amount of water vapor into the sintering atmosphere during the latter stage. It is believed that it is the key factor to raise the O/U ratio of original powder in order to improve the properties of the low-temperature sintered pellets.
Keywords:UO2 pellet  low-temperature sintering  sintering temperature  sintering time
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