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Growth and corrosion behavior of rare earth film on hot-dip galvanized steel
作者单位:College of Materials Science and Engineering South China University of Technology,College of Materials Science and Engineering,South China University of Technology,College of Materials Science and Engineering,South China University of Technology,College of Materials Science and Engineering,South China University of Technology,College of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China,Guangzhou 510640,China,Guangzhou 510640,China,Guangzhou 510640,China,Guangzhou 510640,China
摘    要:1Introduction For a long time,chromate compounds Cr(VI)have been used as effective and inexpensive corrosion inhibitors for zinc and zinc coating.However,with the advent of increasing environmental awareness,the toxicity and carcinogenic nature of Cr(VI)b…

收稿时间:18 February 2006

Growth and corrosion behavior of rare earth film on hot-dip galvanized steel
Authors:Jin-tang LU  Hai-jiang WU  Gang KONG  Chun-shan CHE  Qiao-yu XU
Affiliation:

aCollege of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China

Abstract:Hot-dip galvanized(HDG) steel sheets were treated for 30 s-24 h by the rare earth aqueous solution containing 20 g/L Ce(NO3)3·6H2O, and the growth behavior and corrosion resistance of the rare earth film were investigated by SEM, EDS, AES and NSS. The results reveal that the rare earth film becomes thick while the mass gain of the samples does not distinctly change due to the zinc dissolution with the increase of treatment time. The film grows up more quickly and is apt to cracking in the vicinity of zinc grain boundaries, and eventually the film partly warps and flakes off with increasing film thickness. The NSS results show that the corrosion resistance of the film is dominated by both the film thickness and the cracks. With increasing treatment time, the corrosion resistance of the film increases within 1 h due to the increased film thickness and decreases after 1 h because the cracking and flaking off gradually become dominant factor.
Keywords:rare earth film  hot dip galvanizing  corrosion resistance
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