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Formation mechanism of laser-clad gradient thermal barrier coatings
作者姓名:陈国锋  冯钟潮  梁勇
作者单位:CHEN Guo feng,FENG Zhong chao,LIANG Yong Institute of Metals Research,Chinese Academy of Sciences,Shenyang 110015,P.R.China
摘    要:1 INTRODUCTIONTheZrO2 ceramicswasselectedasthematerialofthermalbarriercoatings (TBCs)foritshighmelt ing pointandhighexpansioncoefficient1].ThemethodtoproduceTBCswasusuallyplasmasprayingtechnique.Theporosityinthecoatingandthepooradherencebetweencoatingands…


Formation mechanism of laser-clad gradient thermal barrier coatings
CHEN Guo-feng,FENG Zhong-chao,LIANG Yong.Formation mechanism of laser-clad gradient thermal barrier coatings[J].Transactions of Nonferrous Metals Society of China,2000,10(1).
Authors:CHEN Guo-feng  FENG Zhong-chao  LIANG Yong
Abstract:The stratified gradient thermal barrier coatings (TBCs) were obtained by laser cladding of ZrO 2 and NiCoCrAlY mixture powder. The coatings were four layer structure: cellular dendritic ZrO 2, dense ZrO 2, Ni based alloy bonding coating and substrate. The formation of the stratified TBCs was attributed to the insolubility of ZrO 2 in the Ni based alloy and the lower density of ZrO 2 than that of Ni based alloy when both of them were in melted condition. The formation of two layered ZrO 2 was related to the presence of Al in the Ni based alloy, i) Al could be preoxidized into Al 2O 3 that could be segregated in the grain boundaries of ZrO 2 during solidification process; ii) Al could be partially preoxidized into Al 2O 3, then Al and Al 2O 3 could be segregated simultaneously at the grain boundaries of ZrO 2 during solidification process. Two formation processes were presented.
Keywords:laser cladding  thermal barrier coatings  formation mechanisms
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