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微量添加Fe元素对CuZrAl块体金属玻璃的结构和力学性能的影响(英文)
引用本文:许宏伟,杜宇雷,邓昱.微量添加Fe元素对CuZrAl块体金属玻璃的结构和力学性能的影响(英文)[J].中国有色金属学会会刊,2012,22(5):1123-1126.
作者姓名:许宏伟  杜宇雷  邓昱
作者单位:南京理工大学材料科学与工程学院,材料评价与设计教育部工程研究中心;江苏省(丹阳)高性能合金材料研究院;南京大学固态微结构国家重点实验室和现代分析中心
基金项目:Project (2010ZDJH10) supported by the Nanjing University of Science and Technology Research Funding, China;Project (BK2007213) supported by the Natural Science Foundation of Jiangsu Province, China
摘    要:使用水淬法制备含微量Fe元素的CuZrAl块体金属玻璃。使用X射线衍射(XRD)检测其结构;采用DSC研究Fe元素的添加对块体金属玻璃热稳定性的影响,微量添加Fe元素显著拓宽了过冷液相区。Cu44Zr48Al7Fe块体金属玻璃的塑性应变约为1.5%。使用透射电子显微镜(TEM)观察其微观结构,结果发现,添加1%~2%Fe(摩尔分数)的CuZrAl合金中出现了相分离的富CuZr非晶相。

关 键 词:块体金属玻璃  微观结构  力学性能  相分离  Fe添加
收稿时间:19 September 2011

Effect of minor-addition of Fe on structural and mechanical properties of CuZrAl bulk metallic glass
XU Hong-wei,DU Yu-lei,DENG Yu.Effect of minor-addition of Fe on structural and mechanical properties of CuZrAl bulk metallic glass[J].Transactions of Nonferrous Metals Society of China,2012,22(5):1123-1126.
Authors:XU Hong-wei  DU Yu-lei  DENG Yu
Affiliation:1. Engineering Research Center of Materials Behavior and Design of Ministry of Education, School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; 2. Jiangsu Institute of Advanced Materials, Danyang 212300, China; 3. National Laboratory of Solid State Microstructures and Center for Materials Analysis, Nanjing University, Nanjing 210093, China
Abstract:The CuZrAl bulk metallic glass with minor-addition of Fe was prepared by rapid quenching method. The structures were examined by X-ray diffraction (XRD). The effect of Fe on the glass-forming ability was studied by differential scanning calorimetry (DSC). The minor-addition of Fe obviously extends the supercooled liquid region ΔTx. The plastic strain of the Cu44Zr48Al7Fe bulk metallic glass is about 1.5%. The microstructures were examined by transmission electron microscopy (TEM). It is found that when 1%-2% Fe (mole fraction) were introduced into the CuZrAl alloy matrix, nanoscale phase separation occurs in the as-prepared Cu44Zr48Al7Fe bulk metallic glass.
Keywords:bulk metallic glass  microstructure  mechanical property  phase separation  Fe addition
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