Correlations among stress corrosion cracking,grain-boundary microchemistry,and Zn content in high Zn-containing Al–Zn–Mg–Cu alloys |
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Affiliation: | 1. Light Alloy Research Institute, Central South University, Changsha 410083, China;2. Collaborative Innovation Center of Advanced Nonferrous Structural Materials and Manufacturing, Central South University, Changsha 410083, China;3. National Key Laboratory of Science and Technology for National Defence on High-Strength Lightweight Structural Materials, Central South University, Changsha 410083, China |
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Abstract: | The correlations among the corrosion behaviour, grain-boundary microchemistry, and Zn content in Al–Zn–Mg–Cu alloys were studied using stress corrosion cracking (SCC) and intergranular corrosion (IGC) tests, combined with scanning electron microscopy (SEM) and high-angle angular dark field scanning transmission electron microscopy (HAADF-STEM) microstructural examinations. The results showed that the tensile strength enhancement of high Zn-containing Al–Zn–Mg–Cu alloys was mainly attributed to the high density nano-scale matrix precipitates. The SCC plateau velocity for the alloy with 11.0 wt.% Zn was about an order of magnitude greater than that of the alloy with 7.9 wt.% Zn, which was mainly associated with Zn enrichment in grain boundary precipitates and wide precipitates-free zones. The SCC mechanisms of different Zn-containing alloys were discussed based on fracture features, grain-boundary microchemistry, and electrochemical properties. |
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Keywords: | Al–Zn–Mg–Cu alloy stress corrosion cracking Zn content grain-boundary microchemistry |
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