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低品位红土镍矿深度还原机理
引用本文:李艳军,孙永升,韩跃新,高鹏. 低品位红土镍矿深度还原机理[J]. 中国有色金属学会会刊, 2013, 23(11): 3428-3433. DOI: 10.1016/S1003-6326(13)62884-8
作者姓名:李艳军  孙永升  韩跃新  高鹏
作者单位:东北大学资源与土木工程学院,沈阳110819
基金项目:Project (51134002) supported by the National Natural Science Foundation of China; Project (2012BAB 14B02) supported by the Ministry of Science and Technology of China; Project (12120113086600) supported by Ministry of Land and Resources of China
摘    要:采用扫描电子显微镜和EDS能谱研究低品位红土镍矿深度还原过程中金属颗粒的生长行为,并在此基础上分析其还原机理。结果表明,金属铁和镍逐渐聚集生长为Fe—Ni颗粒,并且颗粒粒度随着还原温度的升高和还原时间的延长而明显增大。还原后,红土镍矿明显变为Fe—Ni金属颗粒和渣相基体两部分。铁镁橄榄石的还原与其晶体化学特性密切相关。铁和镍的氧化物被还原剂还原为金属铁和镍,同时,橄榄石的晶格结构被破坏。红土镍矿深度还原包含金属氧化物还原和金属相生长两个过程。

关 键 词:红土镍矿  深度还原  还原机理  Fe—Ni金属相
收稿时间:2013-07-29

Coal-based reduction mechanism of low-grade laterite ore
Yan-jun LI,Yong-sheng SUN,Yue-xin HAN,Peng GAO. Coal-based reduction mechanism of low-grade laterite ore[J]. Transactions of Nonferrous Metals Society of China, 2013, 23(11): 3428-3433. DOI: 10.1016/S1003-6326(13)62884-8
Authors:Yan-jun LI  Yong-sheng SUN  Yue-xin HAN  Peng GAO
Affiliation:College of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China
Abstract:A low-grade nickel laterite ore was reduced at different reduction temperatures. The morphology of metallic particles was investigated by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Experimental results indicate that the metallic nickel and iron gradually assemble and grow into larger spherical particles with increasing temperature and prolonging time. After reduction, the nickel laterite ore obviously changes into two parts of Fe-Ni metallic particles and slag matrix. An obvious relationship is found between the reduction of iron magnesium olivine and its crystal chemical properties. The nickel and iron oxides are reduced to metallic by reductant, and the lattice of olivine is destroyed. The entire reduction process is comprised of oxide reduction and metallic phase growth.
Keywords:nickel laterite ore  coal-based reduction  reduction mechanism  Fe-Ni metallic phase
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