Photochemical synthesis of bimetallic Au-Ag nanoparticles with “core-shell”type structure by seed mediated catalytic growth |
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引用本文: | 董守安,唐春.Photochemical synthesis of bimetallic Au-Ag nanoparticles with “core-shell”type structure by seed mediated catalytic growth[J].中国有色金属学会会刊,2005,15(2):310-313. |
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作者姓名: | 董守安 唐春 |
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作者单位: | InstituteofPreciousMetals,Kunming650221,China |
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基金项目: | Project(2000E0008Z) supported by Natural Science Foundation of Yunnan Province |
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摘 要: | The colloidal Au core/Ag shell structure composite nanoparticles were synthesized in PEG-acetone solution by photochemical route. The monodispersed Au nanoparticles with average diameter of 3. 9 nm were used as growth seeds. The optical property of colloids and the sizes of composite nanoparticles were characterized when the molar ratio of Au to Ag ranges from 4:1 to 1:4. The results show that a composite nanoparticle structure similarto strawberry shape is formed at the molar ratio of Au to Ag from 4 : 1 to 1:1;the composite nanoparticles consisting of a core of Au and shell of Ag were generated at the 1:4 molar ratio, having a striking feature of forming interconnected network structure.
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关 键 词: | 金-银胶质 光化学合成 核-壳结构 纳米合金材料 |
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