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Preparation of nanocrystal modificator and its modification mechanism
作者姓名:董天顺  崔春翔  刘双进  杨薇  刘福才
作者单位:School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China
摘    要:In order to increase the modifying effect, the Cu-P master alloy was rapidly solidified with melt-spin method, and the nano-sized ribbon was gained at 10^5-10^6 ℃/s. Subsequently, ZL109 alloy was modified by nanocrystal and massive Cu-P master alloy, respectively, with molten metal casting method. The results show that the microscopic structure of ZL109 alloy modified by nanocrystal Cu-P master alloy is better than that modified by massive Cu-P master alloy, the original crystal silicon and eutectic silicon are refined more effectively and the mechanical properties are increased evidently: the tensile-strength is increased by 25%, the elongation is increased by 32.26% and the hardness is increased by 17.2%. Therefore, the melt-spin treatment is a feasible method to improve the modifying effect of Cu-P master alloy.

关 键 词:铜磷中间合金  ZL109合金  熔化旋转  快速凝固  纳米晶
收稿时间:8 December 2006
修稿时间:2006-12-082007-04-20

Preparation of nanocrystal modificator and its modification mechanism
DONG Tian-shun,CUI Chun-xiang,LIU Shuang-Jin,YANG Wei,LIU Fu-cai.Preparation of nanocrystal modificator and its modification mechanism[J].Transactions of Nonferrous Metals Society of China,2007,17(4):823-827.
Authors:DONG Tian-shun  CUI Chun-xiang  LIU Shuang-Jin  YANG Wei  LIU Fu-cai
Affiliation:School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China
Abstract:In order to increase the modifying effect, the Cu-P master alloy was rapidly solidified with melt-spin method, and the nano-sized ribbon was gained at 105–106 °C/s. Subsequently, ZL109 alloy was modified by nanocrystal and massive Cu-P master alloy, respectively, with molten metal casting method. The results show that the microscopic structure of ZL109 alloy modified by nanocrystal Cu-P master alloy is better than that modified by massive Cu-P master alloy, the original crystal silicon and eutectic silicon are refined more effectively and the mechanical properties are increased evidently: the tensile-strength is increased by 25%, the elongation is increased by 32.26% and the hardness is increased by 17.2%. Therefore, the melt-spin treatment is a feasible method to improve the modifying effect of Cu-P master alloy.
Keywords:Cu-P master alloy  ZL109 alloy  melt-spin  rapid solidification  nanocrystal  modification  refinement
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