Chromium–palladium films on 316L stainless steel by pulse electrodeposition and their corrosion resistance in hot sulfuric acid solutions

Chromium–palladium alloy films with good adhesive strength and higher micro-hardness have been deposited on 316L stainless steel by pulse electroplating. The films are composed mainly of chromium and palladium crystallites in the metallic state, with grain sizes less than 100 nm. On the film surface Cr(OH)₃ and Cr₂O₃ are present. The co-deposited Cr and Pd in the films show a synergetic effect on passivation. In boiling 20 wt.% H₂SO₄ solution, boiling acetic–formic acid mixture, and simulated PEM fuel cells environment, the Cr–Pd-plated 316L steel shows excellent corrosion resistance.