| RuPt双金属在催化加氢反应中的性能研究 |
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| 引用本文： | 刘曼君,王柳枫,王梁炳.RuPt双金属在催化加氢反应中的性能研究[J].贵金属,2021,42(3):21-25. |
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| 作者姓名： | 刘曼君 王柳枫 王梁炳 |
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| 作者单位： | 中南大学 材料科学与工程学院，长沙 410083;浙江新和成股份有限公司，浙江 绍兴 312500 |
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| 基金项目： | 国家自然科学基金项目(51801235)；湖南省自然科学基金(2018RS3019，2019JJ30033) |
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| 摘 要： | 采用溶剂热法制备了5%Pt/C、5%Ru/C和5%Ru95Pt5/C三种催化剂。对催化剂的形貌和活性组分分布进行了表征分析，分别研究了不同催化剂在苯乙炔或4-硝基酚加氢反应中的催化性能。结果表明，由于协同效应，双金属负载的催化剂5%Ru95Pt5/C比单金属催化剂具有更好的催化加氢性能。在苯乙炔加氢反应中，5%Ru95Pt5/C具有更高的选择性和优异的活性；在4-硝基酚的加氢中，5%Ru95Pt5/C的催化活性显著增加，且在循环5次后，仍保留了>99%的活性。
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| 关 键 词： | 双金属 催化加氢 苯乙炔 4-硝基酚 选择性 |
| 收稿时间： | 2020/12/25 0:00:00 |
Research on the properties of RuPt bimetals in catalytic hydrogenation reaction |
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| LIU Man-jun,WANG Liu-feng,WANG Liang-bing.Research on the properties of RuPt bimetals in catalytic hydrogenation reaction[J].Precious Metals,2021,42(3):21-25. |
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| Authors: | LIU Man-jun WANG Liu-feng WANG Liang-bing |
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| Affiliation: | School of Materials Science and Engineering, Central South University, Changsha 410083 China;Zhejiang NHU Company Co.Ltd., Shaoxin 312500, Zhejiang, China |
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| Abstract: | In this paper, 5%Pt/C, 5%Ru/C and 5%Ru95Pt5/C were prepared by a solvent thermal method. Their morphology and composition distribution were characterized and analyzed. The catalytic performance of the catalysts in hydrogenation of phenylacetylene and 4-nitrophenol were studied. The results showed that 5%Ru95Pt5/C had better catalytic performance of hydrogenation than the other two monometallic catalysts because of synergistic effect. In the hydrogenation of phenylacetylene, 5%Ru95Pt5/C had higher selectivity and more excellent activity than other two catalysts. In the hydrogenation of 4-nitrophenol, the catalytic activity of 5%Ru95Pt5/C was significantly increased, and it remained >99% activity after 5 cycles. |
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| Keywords: | bimetallic catalytic hydrogenation phenylacetylene 4-nitrophenol selectivity |
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