| AgCuZnNi合金铸态组织及凝固路径分析 |
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| 引用本文： | 李再久,田娟娟,朱绍武,陈家林,金青林,谢 明.AgCuZnNi合金铸态组织及凝固路径分析[J].贵金属,2016,37(3):6-10, 17. |
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| 作者姓名： | 李再久 田娟娟 朱绍武 陈家林 金青林 谢 明 |
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| 作者单位： | 1. 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室,昆明,650106;2. 昆明理工大学材料科学与工程学院,昆明,650093;3. 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室，昆明 650106; 昆明理工大学材料科学与工程学院，昆明 650093 |
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| 基金项目： | 稀贵金属先进材料协同创新中心协同创新基金(2014XT03)，稀贵金属综合利用新技术国家重点实验室开放课题(SKL-SPM-201545)。 |
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| 摘 要： | 采用扫描电子显微镜、能谱仪以及X射线衍射等技术,对Ag-18Cu-30Zn-2Ni合金的铸态组织、相组成及结构进行了分析。结果表明,合金主要由白色基体、细小片层状共晶胞及直径为2~6μm的黑色颗粒相组成;铸态合金的物相组成为面心立方(fcc)晶格结构的Ag基固溶体相、灰色层状共晶相(Ag+Cu64Zn36)及简单立方(sc)晶格结构的近球形黑色颗粒Cu2Ni Zn相;Ag Cu Zn Ni合金的平衡凝固路径为:L→L+γ→(L+α1)+γ→((α2+β)+α1)+γ。
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| 关 键 词： | 金属材料 AgCuZnNi合金 显微组织 相结构 凝固路径 |
| 收稿时间： | 2016/2/16 0:00:00 |
The Study on Microstructure and Solidification Path of AgCuZnNi Brazing Alloy |
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| LI Zaijiu,TIAN Juanjuan,ZHU Shaowu,CHEN Jialin,JIN Qinglin and XIE Ming.The Study on Microstructure and Solidification Path of AgCuZnNi Brazing Alloy[J].Precious Metals,2016,37(3):6-10, 17. |
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| Authors: | LI Zaijiu TIAN Juanjuan ZHU Shaowu CHEN Jialin JIN Qinglin and XIE Ming |
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| Affiliation: | State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China,State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China,Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China and State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China;Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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| Abstract: | Microstructure and phase structure of as-cast Ag-18Cu-30Zn-2Ni alloy were investigated by means of scanning electron microscope (SEM), energy disperse spectroscopy (EDS) and X-ray diffractometer (XRD). The results indicate that the alloy is mainly composed of the white matrix, fine lamellar eutectic cell and black particles with diameter ranges from 2 to 6 μm. The composition and structure of phases is as below: Ag-based solid solution with face-centered-cubic (fcc) lattice structure, grey lamellar eutectic cell (Ag+Cu64Zn36, fcc) and spherical particle Cu2NiZn with simple-cubic (sc) structure. By combining all the analysis results, solidification path of the AgCuZnNi alloys is obtained:L→L+γ→(L+α1)+γ→((α2+β)+α1) +γ. |
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| Keywords: | metal materials AgCuZnNi alloy microstructure phase structure solidification path |
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