| Rh催化的[5+2]反应及其在有机合成中的应用 |
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| 引用本文： | 周利民,廖霞俐,许 可,陈家林,陈立桥,李俊鹏.Rh催化的[5+2]反应及其在有机合成中的应用[J].贵金属,2015,36(2):84-93. |
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| 作者姓名： | 周利民 廖霞俐 许 可 陈家林 陈立桥 李俊鹏 |
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| 作者单位： | 1. 昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室,昆明,650106
2. 昆明理工大学生命科学与技术学院,昆明,650500 |
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| 基金项目： | 国家科研院所技术开发研究专项，国家自然科学基金，云南锡业集团科技计划项目(2013010504)。 |
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| 摘 要： | Rh催化的5+2]反应是一类高效快速构筑多官能团化七元环的重要方法。介绍了常用的Rh催化剂及其配体;分别基于乙烯基环丙烷(VCP)和劳腾施特劳赫中间体类型的Rh催化5+2]反应;Rh催化的5+2]反应机理;Rh催化的5+2]反应在复杂天然产物合成中的应用。
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| 关 键 词： | 催化化学 Rh催化 [5+2]反应 有机合成 |
| 收稿时间： | 2014/7/10 0:00:00 |
Rh-Catalyzed [5+2] Cycloaddition Reaction and Its Applications in Organic Synthesis |
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| ZHOU Limin,LIAO Xiali,XU Ke,CHEN Jialin,CHEN Liqiao and LI Junpeng.Rh-Catalyzed [5+2] Cycloaddition Reaction and Its Applications in Organic Synthesis[J].Precious Metals,2015,36(2):84-93. |
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| Authors: | ZHOU Limin LIAO Xiali XU Ke CHEN Jialin CHEN Liqiao and LI Junpeng |
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| Affiliation: | ZHOU Limin;LIAO Xiali;XU Ke;CHEN Jialin;CHEN Liqiao;LI Junpeng;State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Kunming Institute of Precious Metals;Faculty of Life Science and Technology, Kunming University of Science and Technology; |
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| Abstract: | The rhodium-catalyzed 5+2] cycloaddition reaction is an important methodology in rapid and efficient synthesis of a variety of multifunctional seven-membered ring. Introduced in this review were common rhodium-catalysts, catalyzed 5+2] cycloaddition reactions, the mechanism involved and potential applications in the synthesis of natural products. |
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| Keywords: | catalytic chemistry Rh catalysis [5+2] cycloaddition reaction organic synthesis |
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