| 多元光谱拟合ICP-AES法同时测定铂中22个杂质元素 |
| |
| 引用本文： | 李光俐,徐光,何姣,刘伟,王应进,贺胜男.多元光谱拟合ICP-AES法同时测定铂中22个杂质元素[J].贵金属,2010,31(4). |
| |
| 作者姓名： | 李光俐 徐光 何姣 刘伟 王应进 贺胜男 |
| |
| 作者单位： | 贵研铂业股份有限公司,稀贵金属综合利用新技术国家重点实验室,云南,昆明,650106 |
| |
| 基金项目： | 贵研铂业研究与开发基金项目(No.GY-08-RDS35)资助 |
| |
| 摘 要： | 试样用HCl-HNO3溶解,采用多元光谱拟合(MSF)功能ICP-AES法同时测定铂中22个杂质元素:Pd、Rh、Ir、Ru、Au、Ag、Cu、Fe、Zn、Ni、Mn、Cr、Mg、Cd、Al、Ca、Pb、Sn、Bi、Si、Mo、Ti。对基体铂的影响、MSF功能、元素分析谱线、背景校正、仪器分析参数等进行了研究,确定了最佳实验条件。杂质元素测定范围Ag、Pd、Cu、Cr、Ti、Mn和Mo为0.0004%~0.05%;Rh、Ir、Pb、Fe、Mg、Al、Zn、Si、Bi、Ca、Cd、Sn、Au和Ni为0.0005%~0.05%;Ru为0.001%~0.05%;方法的相对标准偏差(RSD)和加标回收率分别为1.5%~8.1%和85.1%~118.5%。方法准确、快速、简便,已用于铂中杂质元素的分析。
|
| 关 键 词： | 分析化学 多元光谱拟合(MSF) 电感耦合等离子体原子发射光谱法 铂 杂质元素 |
MSF for Determination of 22 Impurities in Pure Platinum by ICP-AES |
| |
| LI Guangli,XU Guang,HE Jiao,LIU Wei,WANG Yingjin,HE Shengnan.MSF for Determination of 22 Impurities in Pure Platinum by ICP-AES[J].Precious Metals,2010,31(4). |
| |
| Authors: | LI Guangli XU Guang HE Jiao LIU Wei WANG Yingjin HE Shengnan |
| |
| Affiliation: | LI Guangli,XU Guang,HE Jiao,LIU Wei,WANG Yingjin,HE Shengnan(State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co.Ltd.,Kunming 650106,Yunnan,China) |
| |
| Abstract: | A new method of MSF for determination of 22 impurities by ICP-AES has developed.These impurities including Pd,Rh,Ir,Ru,Au,Ag,Cu,Fe,Zn,Ni,Mn,Cr,Mg,Cd,Al,Ca,Pb,Sn,Bi,Si,Mo and Ti in pure platinum.The samples were dissolved in HCl-HNO3 prior to the measurments.The influencing factors,such as interference of platinum,MSF,spectra of analyzed element,background correction and instrument parameters,were investigated.The determination levels are in the range from 0.0004% to 0.05% for Ag,Pd,Cu,Cr,Ti,Mn and Mo,from 0... |
| |
| Keywords: | analytical chemistry MSF ICP-AES platinum impurities |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
