| 铂族金属均相催化剂的研究和应用 |
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| 引用本文： | 潘再富,刘伟平,陈家林,夏永明. 铂族金属均相催化剂的研究和应用[J]. 贵金属, 2009, 30(3) |
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| 作者姓名： | 潘再富 刘伟平 陈家林 夏永明 |
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| 作者单位： | 昆明贵金属研究所,云南,昆明,650106 |
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| 基金项目： | 云南省重大科技计划项目 |
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| 摘 要： | 铂族金属均相催化剂是一类特殊结构的金属配合物,具有均相催化氢化反应、羰基加成反应、酰氢化反应、烯烃氧化反应、C-C合成反应等的作用, 在现代化学和制药工业中得到重要的应用.涉及的催化机理主要包括氧化加成、分子内配体重排、配体迁移和插入、还原消除.论文介绍和讨论了铂族金属均相催化剂的历史、应用、催化机制和最新的进展.
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| 关 键 词： | 催化剂 铂族金属 均相催化 机理 应用 |
Research and Application of Platinum Metal Homogeneous Catalysts |
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| PAN Zaifu,LIU Weiping,CHEN Jialin,XIA Youming. Research and Application of Platinum Metal Homogeneous Catalysts[J]. Precious Metals, 2009, 30(3) |
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| Authors: | PAN Zaifu LIU Weiping CHEN Jialin XIA Youming |
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| Affiliation: | Kunming Institute of Precious Metals;Kunming;Yunnan 650106;China |
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| Abstract: | Platinum metal homogeneous catalysts are a kind of metal coordination compounds with unique chemical structures.They are able to catalyze effectively many reactions including hydrogenation,carbonylation,hydroformylation,oxidation of alkenes and C-C bond formation and so on,and have been used in small-scale laboratory preparations and increasingly in industrially areas especially in the pharmaceutical industry.The catalystic mechanism involves oxidative addition,intramolecular ligand rearrangement,ligand mig... |
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| Keywords: | catalysts platinum group metals homogeneous catalysis mechanism application |
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