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某304不锈钢管道泄漏的失效分析
引用本文:蒋志国,王辉煌,龚利华.某304不锈钢管道泄漏的失效分析[J].腐蚀与防护,2017,38(2).
作者姓名:蒋志国  王辉煌  龚利华
作者单位:1. 江苏省特种设备安全监督检验研究院常熟分院,常熟,215550;2. 江苏科技大学材料科学与工程学院,镇江,212003
摘    要:某氟化工企业304不锈钢管道在运行三年半后发生泄漏失效。通过直读光谱仪、光学显微镜、扫描电镜和X射线衍射仪等对失效部位材料的化学成分、显微组织、腐蚀形貌及腐蚀产物进行了分析。结果表明:该304不锈钢管道的失效主要为Cl-浓缩造成的点蚀穿孔,H_2S的存在则对点蚀起到了促进作用。

关 键 词:不锈钢  失效分析  点蚀  H2S

Analysis of Leakage Failure of a Type 304 Stainless Steel Tube
JIANG Zhi-guo,WANG Hui-huang,GONG Li-hua.Analysis of Leakage Failure of a Type 304 Stainless Steel Tube[J].Corrosion & Protection,2017,38(2).
Authors:JIANG Zhi-guo  WANG Hui-huang  GONG Li-hua
Abstract:Leakage failure occurred at a 304 stainless steel tube after working for three and a half years in a fluorine chemical enterprise.The chemical composition,microstructure,corrosion morphology and corrosion products of the material in failed part of 304 stainless steel tube were studied using direct reading spectrometry,optical microscopy,scanning electron microscopy and X-ray diffraction.The results show that the major failure mode was pitting corrosion and perforation due to local enrichment of Cl-in the tube,and the existence of H2S promoted pitting corrosion.
Keywords:stainless steel  failure analysis  pitting corrosion  H2S
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