| 金属表面席夫碱缓蚀剂自组装膜的制备及性能研究现状 |
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| 引用本文： | 陈世亮,刘峥,张小鸽.金属表面席夫碱缓蚀剂自组装膜的制备及性能研究现状[J].腐蚀与防护,2011(4):326-330. |
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| 作者姓名： | 陈世亮 刘峥 张小鸽 |
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| 作者单位： | 桂林理工大学化学与生物工程学院; |
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| 基金项目： | 广西高校优秀人才资助计划项目(No.RC2007021); 广西研究生教育创新计划项目(2009105960817M22); 广西研究生教育创新人才联合培养基地项目 |
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| 摘 要： | 席夫碱是由伯胺与活性羰基缩合而成的含有甲亚胺活性基团-RC=N-的一类有机化合物,能在金属表面发生化学吸附反应而形成结构稳定、排列紧密有序的自组装膜(SAMs);SAMs是一种有缓蚀性能的单分子膜,对基底金属有良好的防腐蚀作用.本文综述了近年来席夫碱类自组装膜的制备方法及自组装膜的表征技术,进一步概述了分子模拟及拓扑结...
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| 关 键 词： | 金属 自组装膜 席夫碱 制备 缓蚀 量子化学 |
Research Status of Preparation and Properties of Self-assembled Monolayers of Schiff Base on Metal Surface |
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| CHEN Shi-liang,LIU Zheng,ZHANG Xiao-ge.Research Status of Preparation and Properties of Self-assembled Monolayers of Schiff Base on Metal Surface[J].Corrosion & Protection,2011(4):326-330. |
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| Authors: | CHEN Shi-liang LIU Zheng ZHANG Xiao-ge |
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| Affiliation: | CHEN Shi-liang,LIU Zheng,ZHANG Xiao-ge (College of Chemical and Biological Engineering,Guilin University of Technology,Guilin 541004,China) |
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| Abstract: | Shiff bases are a class of organic compounds containing azomethine active groups-RC=N-,synthesized by the condensation of primary amine and active carbonyl.Shiff bases could form self-assembled monolayers(SAMs) through chemical adsorption on metal surface,stable and compactly arranged.SAMs are corrosion inhibition molecular films and have good corrosion resistance for the metal substrate.The methods of preparation and characterization of self-assembled monolayers(SAMs) are reviewed,the application status of... |
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| Keywords: | metal self-assembled monolayer schiff base preparation corrosion inhibition quantum chemistry |
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