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Crystal structures of the Ag4HgGe2S7 and Ag4CdGe2S7 compounds
Authors:L D Gulay  I D Olekseyuk and O V Parasyuk
Affiliation:

a Fachbereich Chemie der Philipps-Universität, D-35032 Marburg, Germany

b Department of General and Inorganic Chemistry, Volyn State University, Voli Ave 13, 43025 Lutsk, Ukraine

Abstract:The crystal structures of the Ag4HgGe2S7 and Ag4CdGe2S7 compounds were investigated using X-ray powder diffraction. These compounds crystallize in the monoclinic Cc space group with the lattice parameters a=1.74546(8), b=0.68093(2), c=1.05342(3) nm, β=93.398(3)° for Ag4HgGe2S7 and a=1.74364(8), b=0.68334(3), c=1.05350(4) nm, β=93.589(3)° for Ag4CdGe2S7. Atomic parameters were refined in the isotropic approximation (RI=0.0761 and RI=0.0727, respectively).
Keywords:Semiconductors  Crystal structure  X-ray diffraction
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