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Synthesis of MnO/C composites through a solid state reaction and their transformation into MnO2 nanorods
Authors:Qin HaoLiqiang Xu  Guangda LiZhicheng Ju  Changhui sunHouyi Ma  Yitai Qian
Affiliation:a Key Laboratory of Colloid and Interface Chemistry (Shandong University), Ministry of Education, Shanda nanlu 27, Jinan, Shandong 250100, PR China
b University of Science and Technology of China, Hefei, Anhui 230026, PR China
Abstract:MnO nanospheres encapsulated in carbon (MnO/C) composites were synthesized through a one-step solid state reaction between potassium permanganate and salicylic acid at 700 °C, which could be transformed into MnO2 nanorods after being annealed in ambient atmosphere. Their formation mechanisms and electrochemical performances as anodes in Li-ion batteries (LIBs) were investigated. The first discharge capacity of MnO/C composites was 585.9 mA h g−1, while that of MnO2 was 1269 mA h g−1, indicating their potential applications in LIBs.
Keywords:Composite materials  Oxide materials  Solid state reactions
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