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双氧水-硫酸酸蚀对酚醛塑料/化学镀镍层结合力的影响
引用本文:刘磊,梁小平,颜贵龙.双氧水-硫酸酸蚀对酚醛塑料/化学镀镍层结合力的影响[J].表面技术,2011,40(1):25-27,30.
作者姓名:刘磊  梁小平  颜贵龙
作者单位:天津工业大学,中空纤维膜材料与膜过程省部共建国家重点实验室培育基地,天津,300160;天津工业大学,材料科学与工程学院,天津,300160;天津工业大学,中空纤维膜材料与膜过程省部共建国家重点实验室培育基地,天津,300160;天津工业大学,材料科学与工程学院,天津,300160;天津工业大学,中空纤维膜材料与膜过程省部共建国家重点实验室培育基地,天津,300160;天津工业大学,材料科学与工程学院,天津,300160
基金项目:天津市应用基础及前沿技术研究计划重点项目
摘    要:利用双氧水-硫酸混合溶液对酚醛塑料进行不同时间的酸蚀处理,之后在塑料表面化学镀镍,采用红外光谱、SEM表征了塑料表面的基团及塑料/镀层界面的形貌,分析了酸蚀时塑料表面亲水性和塑料/化学镀镍层结合力的影响.研究结果表明:酸蚀处理3 min后,酚醛塑料表面因氧化形成磺酸基亲水基团,导致表面由酸蚀前的疏水性转变为亲水性;酸蚀...

关 键 词:酚醛塑料  化学镀镍  双氧水-硫酸  酸蚀  亲水性  结合强度

Effect of the Hydrogen Peroxide-Sulphuric Acid Etching on the Adhesion of Electroless Nickel Plating to Phenolic Plastic
LIU lei,LIANG Xiao-ping,YAN Gui-long.Effect of the Hydrogen Peroxide-Sulphuric Acid Etching on the Adhesion of Electroless Nickel Plating to Phenolic Plastic[J].Surface Technology,2011,40(1):25-27,30.
Authors:LIU lei  LIANG Xiao-ping  YAN Gui-long
Affiliation:LIU lei1,2,LIANG Xiao-ping1,YAN Gui-long1,2(1.State Key Laboratory of Hollow Fiber Membrane Material and Process,Tianjin Polytechnic University,Tianjin 300160,China,2.School of Materials Science and Engineering,China)
Abstract:The phenolic plastics(PF) were acid-etched with the mixture of hydrogen peroxide-sulphuric acid for different time,then were surface modified by electroless nickel plating(ENP),the groups of PF surface and the morphology of interface between PF and ENP were characterized by the inrared spectrum(IR) and scanning electron microscope(SEM),the effects of the acid-etching on the surface hydrophilicity of the PF and the adhesion of the ENP to the PF were investigated.The results show that the PF surface is oxidiz...
Keywords:phenolic plastic  electroless nickel plating  hydrogen peroxide-sulphuric acid  acid-etching  hydrophilicity  adhesion strength  
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