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Mg-1lLi-3AI-O. 5RE合金在酸性NaCI溶液中腐蚀特性研究
引用本文:高丽丽,张春红,黄晓梅,张密林.Mg-1lLi-3AI-O. 5RE合金在酸性NaCI溶液中腐蚀特性研究[J].表面技术,2008,37(2):4-7.
作者姓名:高丽丽  张春红  黄晓梅  张密林
作者单位:哈尔滨工程大学超轻材料与表面技术重点实验室,黑龙江,哈尔滨,150001
摘    要:为研究Mg-11Li-3Al-0.5RE合金在酸性NaCl溶液中的腐蚀特点,采用静态失重法和电化学方法对合金的腐蚀行为进行测试,并用SEM、XRD分别分析了腐蚀形貌和腐蚀产物.结果表明:在酸性NaCl溶液中,随着Cl-含量的升高,合金的平均腐蚀速率增大,腐蚀电位负移,体系中Rsol、Rt、Rf减小,腐蚀越严重; pH值减小时,合金的腐蚀电流增大,线性极化电阻减小,加快了腐蚀的进行.在酸性环境中,Mg-11Li-3Al-0.5RE合金腐蚀后形成较大、较深的蚀坑,腐蚀产物主要为Mg(OH)2和Al2O3.

关 键 词:Mg-11Li-3Al-0.5RE合金  酸性  NaCl溶液  腐蚀
文章编号:1001-3660(2008)02-0004-04
收稿时间:2007/12/19 0:00:00
修稿时间:2007年12月19

Study on Corrosion Characteristic of Mg-1lLi-3AI-0.5RE Alloy in Acidic Solution of NaCI
GAO Li-Ii,ZHANG Chun-hong,HUANG Xiao-mei and ZHANG Mi-Iin.Study on Corrosion Characteristic of Mg-1lLi-3AI-0.5RE Alloy in Acidic Solution of NaCI[J].Surface Technology,2008,37(2):4-7.
Authors:GAO Li-Ii  ZHANG Chun-hong  HUANG Xiao-mei and ZHANG Mi-Iin
Affiliation:Key Laboratory of Superlight Materials and Surface Technology, Harbin Engineering University, Harbin 150001, China,Key Laboratory of Superlight Materials and Surface Technology, Harbin Engineering University, Harbin 150001, China,Key Laboratory of Superlight Materials and Surface Technology, Harbin Engineering University, Harbin 150001, China and Key Laboratory of Superlight Materials and Surface Technology, Harbin Engineering University, Harbin 150001, China
Abstract:Corrosion behavior of Mg-1lLi-3Al-O. SRE alloy in acidic solution of NaCl was investigated by means of weight loss and electrochemical means. The corrosion appearance and corroded surface were analyzed by using SEM and XRD. The results showed that the average corrosion velocity of Mg-1lLi-3Al-O. SRE alloy increased, nevertheless the pitting corrosion potential, Rsol, Rt, and Rf decreased when the concentration of Cl- increased in acidic solution of NaCl. This means that corrosion developed more seriously with the increase of Cl- concentration. The corrosion current gradually increased while linear resistance decreased with the decrease of pH value, so that the corrosion reaction was picked up. In acidic solution of NaCI, the deep corrosion pits were formed after corrosion experiments, and the corrosion products on alloys surface were mainly consisted of Mg( OH)2 and Al203.
Keywords:Mg-1lLi-3Al-O  SRE alloy  Acidic    NaCI solution    Corrosion
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