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酸洗缓蚀剂对冷轧钢板磷化处理的影响
引用本文:许斌,刘春明,郝建军,安成强.酸洗缓蚀剂对冷轧钢板磷化处理的影响[J].表面技术,2010,39(5):48-50.
作者姓名:许斌  刘春明  郝建军  安成强
作者单位:东北大学材料与冶金学院,沈阳,110819;河北钢铁集团邯钢公司,邯郸,056015;东北大学材料与冶金学院,沈阳,110819;沈阳理工大学环境与化工学院,沈阳,110159;东北大学金属防护技术工程研究中心,沈阳,110819
摘    要:采用乌洛托品、硫脲、乌洛托品-碘化钾、硫脲-硫酸铝4种酸洗缓蚀剂,在不同浓度的条件下对冷轧钢板进行酸洗,再对酸洗的钢板进行磷化处理,研究了酸洗缓蚀剂对磷化膜外观形貌、厚度、耐蚀性的影响.结果表明:酸洗液中使用不同的缓蚀剂对磷化膜外观、膜重与耐蚀性有明显的影响,乌洛托品和硫脲-硫酸铝的影响低于硫脲和乌洛托品-碘化钾;乌洛托品、硫脲、硫脲-硫酸铝在酸洗液中的质量分数分别不高于0.3%,1.0%,1.5%时,满足使用要求.

关 键 词:冷轧钢板  酸洗  缓蚀剂  磷化
修稿时间:2010/10/10 0:00:00

The Influence of Corrosion Inhibitor for Pickling on Phosphating of Cold-roll Steel Sheets
XU Bin,LIU Chun-ming,HAO Jian-jun and AN Cheng-qiang.The Influence of Corrosion Inhibitor for Pickling on Phosphating of Cold-roll Steel Sheets[J].Surface Technology,2010,39(5):48-50.
Authors:XU Bin  LIU Chun-ming  HAO Jian-jun and AN Cheng-qiang
Affiliation:1.School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China;2.Hebei Iron& Steel Group Co. Ltd, Hebei,Handan 056015, China,School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China,1.School of Environment& Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China;2.Engineering Research Center of Metal Protection Technology, Northeastern University, Shenyang 110819, China and 1.School of Environment& Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China;2.Engineering Research Center of Metal Protection Technology, Northeastern University, Shenyang 110819, China
Abstract:Using different concentrations of four pickling corrosion inhibitor, that included the methenamine, thiourea, methenamine-potassium iodide and thiourea-aluminum sulfate, first cold-rolled steel sheets were cleaned by pickling, then they were phophated by acid.In this time,theinfluence of differentpickling corrosioninhibitoron the appearance,the coating hardness and the corrosion resistance of phosphating films were researched. The result shows that the influence of different corrosion inhibitor is obvious for the appearance, the coating hardness and the corrosion resistance of phosphating films in pickling solutions. The influence of methenamine and thiourea-aluminum sulfate for phosphating films is lower than the influence of thiourea and methenamine-potassium iodide. The phosphating is suitable when corrosion inhibitor'' s using concentration is no more than 0.3%,1.0%, 1.5% for methenamine, thiourea, and thiourea-aluminum sulfate.
Keywords:cold-rolled steel sheets  pickling  corrosion inhibitor  phosphating
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