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Au-Cu合金的微观结构和性质
引用本文:谢佑卿,张晓东.Au-Cu合金的微观结构和性质[J].金属学报,1994,30(12):531-539.
作者姓名:谢佑卿  张晓东
作者单位:中南工业大学
摘    要:依据建立在统计热力学和金属电子理论基础上的合金综合理论──合金相的特征晶体理论,对Au-Cu合金的微观结构和性质进行了研究.确定了特征性质(势能和体积)的相互作用方程,各特征原子的电子结构及演变特点;计算了合金的形成热、混合Gibbs自由能和晶格常数随成分的变化.这些性质的理论值和实验值符合很好。

关 键 词:Au-Cu合金,电子结构,原子组态,形成热,晶格常数

MICROSTRUCTURE AND PROPERTIES OF Au-Cu ALLOYS
XIE Youqing,ZHANG Hiaodong.MICROSTRUCTURE AND PROPERTIES OF Au-Cu ALLOYS[J].Acta Metallurgica Sinica,1994,30(12):531-539.
Authors:XIE Youqing  ZHANG Hiaodong
Affiliation:XIE Youqing,ZHANG Hiaodong(Central South University of Technology,Changsha)
Abstract:According to characteristic crystal theory of alloy phases established on the statistic thermodynamics and electronic theory of metals,a systematic analysis has been conducted on the Au-Cu system. The interaction equations of characteristic properties (energy and volume),electronic structures and their changing characters of characteristic atoms in the Au-Cu alloys have been determined. The theoretical values of heat of formation, mixing Gibbs free energy and lattice constant as a function of concentration are in good agreement with the experimental values.XIE
Keywords:Au-Cu alloy  electronic structure  atomic configuration  heat of formation  lattice constant
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