Effect of Post-weld Heat Treatment on the Microstructure and Corrosion Resistance of Deposited Metal of a HighChromium Nickel-Based Alloy |
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Authors: | Xin-Jie Di Xiao-Qian Liu Cui-Xin Chen Bao-Sen Wang Xiao-Jiang Guo |
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Affiliation: | 1. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China2. School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300130, China3. Baosteel Research Institute, Baoshan Iron &Steel Co., Ltd.,Shanghai 200431, China;4. National Engineering Laboratory of Transportation Safety of Oil & Gas Pipeline, Langfang 065000, China; |
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Abstract: | The evolution of Cr23C6 carbides in the deposited metal (DM) of a high-chromium nickel-based alloy was investigated after the post-weld heat treatment (PWHT) at 650, 750, 850, and 950 °C, respectively. With the increase in temperature, the morphology of the Cr23C6 carbides at the grain boundaries was transformed from the continuous lamellar-like to the semi-continuous rod-like and then to the discontinuous granular. Besides, the needle-like Cr23C6 carbides precipitated from γ matrix after PWHT at 850 °C. The coarsening kinetics of the needle-like Cr23C6 carbides obeyed the Lifshitz-Slyozov-Wagner law with the growth speed of 4.93 μm3/h in length and 5.56 × 10-3 μm3/h in width. Moreover, the ratio of the carbide length to width increased rapidly at first and then flattened as the holding time increased to 850 °C. The results of electrochemical corrosion experiment indicated that the needled-like Cr23C6 carbides impaired the corrosion resistance of DM due to the formation of chromium depletion around the carbides. |
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Keywords: | Post-weld heat treatment Carbide precipitatio nMorphology evolution Electrochemical behavior |
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