Impacts of Microalloying Elements on the Hardening β"-Phase in Automotive AlMgSi Alloys |
| |
Authors: | Zhaoqun Chen Yuxiang Lai Linghong Liu Ziran Liu Jianghua Chen |
| |
Affiliation: | 1.Center for High-Resolution Electron Microscopy, College of Materials Science & Engineering, Hunan University, Changsha 410082, Hunan, China;2.College of Science, Central South University of Forestry and Technology, Changsha 410004, China;3.Department of Physics and Key Laboratory for Low-Dimensional Structures and Quantum Manipulation (Ministry of Education), Hunan Normal University, Changsha 410081, China |
| |
Abstract: | Microalloying elements play a crucial role in mechanical properties and phase stability of metallic alloys. In this work, we employ first-principles calculations and atomic-scale high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) to find promising microalloying elements that will improve the stability and properties of β"/Al interface and β" phase in Al-Mg-Si alloys. First, we define a substitution energy for evaluating the stability of β" phase and β"/Al interface with microalloying elements doped. Then, experiments of HAADF-STEM imaging are carried out to verify the calculational results. Next, using the most stable structures doped with microalloying elements, the mechanical properties of the β" bulk and the β"/Al interface were calculated and analyzed. At last, we have figured out the effects of all considered microalloying elements and obtained a rule that the stable occupancy of solute atoms is related to their own radius and the radius of Mg, Si, and Al. These findings will provide some theoretical basis for future microalloying strategies of Al-Mg-Si alloys. |
| |
Keywords: | Al-Mg-Si alloy Microalloying Precipitate Crystal structure Elastic properties First-principles calculations |
|
| 点击此处可从《金属学报(英文版)》浏览原始摘要信息 |
|
点击此处可从《金属学报(英文版)》下载全文 |
|