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纳米Cu颗粒的分散与分级
引用本文:邓晓臣,罗江山,唐永建,韩尚君,李凯,张洪亮.纳米Cu颗粒的分散与分级[J].金属功能材料,2010,17(3):37-41.
作者姓名:邓晓臣  罗江山  唐永建  韩尚君  李凯  张洪亮
作者单位:1. 西南科技大学材料科学与工程学院,四川,绵阳,621010;中国工程物理研究院激光聚变研究中心,四川,绵阳,621900
2. 中国工程物理研究院激光聚变研究中心,四川,绵阳,621900
摘    要:采用自悬浮定向流法制备的纳米Cu粉末具有一定的粒径分布范围,获得分布更窄、更均一的纳米粉末具有重要的应用价值,以达到更加突出的物理性质。本文通过测定纳米Cu-水悬浮液的Zeta电位和吸光度,探讨了不同pH值下以及不同浓度下的十二烷基磺酸钠(SDS)对纳米Cu粉末在水中分散性的影响。结果表明:Zeta绝对值越大,分散稳定性越好。在0.01%纳米Cu-水悬浮液中,在pH值为8.5,SDS分散剂加入量为0.024%(质量)时,分散性最好。在此条件下观察沉降颗粒,在4~8 h时间段内得到的沉降颗粒平均粒径为62 nm单分散性较好的颗粒,且为主要产物。

关 键 词:纳米Cu粉末  Zeta电位  吸光度  DLVO理论  分级

Dispersion and Classification of Nano-CU Powder
DENG Xiao-chen,LUO Jiang-shan,TANG Yong-jian,HAN Shang-jun,LI Kai,ZHANG Hong-liang.Dispersion and Classification of Nano-CU Powder[J].Metallic Functional Materials,2010,17(3):37-41.
Authors:DENG Xiao-chen  LUO Jiang-shan  TANG Yong-jian  HAN Shang-jun  LI Kai  ZHANG Hong-liang
Affiliation:1.Institute of Material Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,Sichuan,China;2.Research Center of Laser Fusion,CAEP.Mianyang 621900,Sichuan,China)
Abstract:The nano-Cu powder are in a certain range of particle size distribution prepared by flow-levitation technology.The exploration is aim at making the distribution of the powder more narrow and more uniform,in order to achieve a more prominent physical properties.Dispersion and stability of nano-Cu particles in water were studied under different pH values and dispersant concentration by the method of Zeta potential and absorbency.The results show that: the higher Zeta potential is,the better dispersion and stability of nano-Cu/water suspension are.When the dispersion and stability of 0.01% nano-Cu/water suspension is the best,pH 8.5 can be selected as an operating pH,and the 0.024% SDS can be selected as an optimizing concentration.Observing the sedimentation particles under these conditions,the average particle size is about 62 nm from 4 to 8 h period of time and as the main product.
Keywords:nano-Cu powder  Zeta potential  absorbency  DLVO theory  classification
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