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三效催化剂用储氧材料铈锆氧化物固溶体的制备
引用本文:王莉,张力.三效催化剂用储氧材料铈锆氧化物固溶体的制备[J].金属功能材料,2011,18(3):74-78.
作者姓名:王莉  张力
作者单位:北京有色金属研究总院,北京,100088
摘    要:铈锆氧化物固溶体由于具有优良的储氧、释放氧的功能而在汽车尾气三效催化剂中得到广泛应用.制备铈锆氧化物固溶体的方法主要有共沉淀法、反相微乳法和溶胶-凝胶法(s01-gel).共沉淀法工艺简单,易操作,便于大规模实施;反相微乳法以微乳液作为反应介质,可以很好的控制粒子的半径,制备纳米固溶体;采用溶胶-凝胶法能制备出高纯度的...

关 键 词:铈锆氧化物固溶体  共沉淀法  反相微乳法  溶胶-凝胶法

Preparation of Ceria-Zirconia Solid Solution in Three-way Catalysts
WANG Li,ZHANG Li.Preparation of Ceria-Zirconia Solid Solution in Three-way Catalysts[J].Metallic Functional Materials,2011,18(3):74-78.
Authors:WANG Li  ZHANG Li
Affiliation:(Beijing General Research Institute for Non-ferrous Metals,Beijing 100088,China)
Abstract:Due to the excellent ability of ceria-zirconia solid solution to act as an oxygen store by storing/releasing O2,it's been used widely in three-way catalyst.The main methods of preparing the solid solution are co-precipitation,reversed microemulsion method and sol-gel.The co-precipitation method is easy to carry out,so it's suitable to be applied in the industry.While the reversed micro-emulsion method is used,reversed micelles are created as reactors to obtain ultrafine and monodispersed nanoparticles.The ceria-zirconia solid solution of high purity can be obtained through sol-gel method.Besides,there're other ways to prepare the solid solution.However,each method has its own advantages and disadvantages,and the properties of the ceria-zirconia solid solution,such as chemical,physical characteristics and catalytic performance,etc.are determined by the preparation methods.
Keywords:ceria-zirconia solid solution  co-precipitation  reversed micro-emulsion method  sol-gel method
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