| 柠檬酸盐凝胶法制备纳米晶SnO2的络合过程及其相结构研究 |
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| 引用本文： | 邵艳群,唐电.柠檬酸盐凝胶法制备纳米晶SnO2的络合过程及其相结构研究[J].金属热处理,2006,31(12):16-18. |
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| 作者姓名： | 邵艳群 唐电 |
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| 作者单位： | 福州大学,材料研究所,福建,福州,350002 |
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| 基金项目： | 国家自然科学基金;福建省科技三项费资助项目 |
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| 摘 要： | 以SnCl2和柠檬酸为前驱物，无水乙醇为溶剂制备了纳米级SnO2。采用红外光谱（FTr—IR）、XRD和TEM测试技术研究了产物的络合过程和组织结构。结果表明，制备过程中形成了柠檬酸锡，其结构特征主要为双齿配位，部分为桥式配位，热处理后的粉体为10nm左右的分散性良好、尺寸分布均匀、具有优良热稳定性的金红石SnO2，形貌为等轴晶。
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| 关 键 词： | 柠檬酸盐凝胶法 纳米晶 组织结构 SnO2粉体 |
| 文章编号： | 0254-6051（2006）12-0016-03 |
| 收稿时间： | 2006-06-12 |
| 修稿时间： | 2006-06-12 |
Complexation and Structures of Nanocrystalline SnO2 Powders Prepared by the Citrate-Gel Method |
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| SHAO Yan-qun,TANG Dian.Complexation and Structures of Nanocrystalline SnO2 Powders Prepared by the Citrate-Gel Method[J].Heat Treatment of Metals,2006,31(12):16-18. |
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| Authors: | SHAO Yan-qun TANG Dian |
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| Affiliation: | Institute for Materials Research, Fuzhou University, Fuzhou Fujian 350002, China |
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| Abstract: | Nanocrystalline SnO2 powders had been synthesized by the citrate-gel method using SnCl2 and citric acid as precursors and anhydrous ethanol as solvent. The complexation and structures of the derived powders were characterized by FT-IR, XRD and TEM techniques. The results show that the tin citrate formed during the synthesis process with structure mainly in two-tooth coruplexing and partly in bridge complexing. The rutile-type SnO2 powders with sizes of uniform distribution around 10 nm and good thermal resistant properties were obtained after heat treatment. |
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| Keywords: | citrate-gel method nanocrystalline structure tin oxide powders |
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