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Properties and microstructure of NiO/SDC materials for SOFC anode applications
作者姓名:CHENG  Jigui  DENG  Liping  ZHANG  Benrui  SHI  Ping  MENG  Guangyao
作者单位:[1]Department of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China [2]Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
基金项目:国家重点基础研究发展计划(973计划)
摘    要:NiO/SDC composites and Ni/SDC cermets for solid oxide fuel cell (SOFC) anode applications were prepared from nickel oxide (NiO) and samada doped ceria (SDC) powders by the powder metallurgy process. The physical and mechanical properties, as well as the microstructure of the NiO/SDC composites and the Ni/SDC cermets were investigated. It is shown that the sintedng temperature of the NiO/SDC composites and NiO content plays an important role in determining the microstructure and properties of the NiO/SDC composites, which, in turn, influences the microstructure, electrical conductivity, and mechanical properties of the Ni/SDC cermets. The present study demonstrated that composition and tprocess parameters must be appropriately selected to optimize the microstructure and the properties of NiO/SDC materials for solid oxide fuel cell applications.

关 键 词:固体燃料电池  阳极  NiO/SDC材料  性质  显微结构
收稿时间:2006-01-10

Properties and microstructure of NiO/SDC materials for SOFC anode applications
CHENG Jigui DENG Liping ZHANG Benrui SHI Ping MENG Guangyao.Properties and microstructure of NiO/SDC materials for SOFC anode applications[J].Rare Metals,2007,26(2):110-117.
Authors:CHENG Jigui  DENG Liping  ZHANG Benrui  SHI Ping  MENG Guangyao
Affiliation:1. Department of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China;2. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China;1. University of Ljubljana, Faculty of Chemistry and Chemical Technology, Aškerčeva 5, 1000 Ljubljana, Slovenia;2. Center of Excellence Low-Carbon Technologies (CO-NOT), Hajdrihova 19, 1000 Ljubljana, Slovenia;1. Department of Mechanical Convergence Engineering, Hanyang University, 222 Wangsimni-ro Seongdong-gu, Seoul, 133-791, Republic of Korea;2. Department of Mechanical Engineering, Stanford University, 440 Escondido Mall, Stanford, CA, 94305, USA;3. Institute of Nano Science and Technology, Hanyang University, 222 Wangsimni-ro Seongdong-gu, Seoul, 133-791, Republic of Korea;1. Materials Science and Engineering Postgraduate Program, UFRN, 59078-970 Natal, Brazil;2. Department of Materials and Ceramic Engineering, University of Aveiro, 3810-193 Aveiro, Portugal;3. Department of Mechanical Engineering, University of Aveiro, 3810-193 Aveiro, Portugal;4. Materials Science and Engineering Postgraduate Program, UFPB, 58051-900 João Pessoa, Brazil;1. Key Laboratory of Physics and Technology for Advanced Batteries, Ministry of Education, College of Physics, Jilin University, Changchun, 130012, China;2. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Physics and Electronic Science, Hubei University, Wuhan, 430062, Hubei, China;3. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore;4. Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, 49931-1295, MI, USA;1. School of Science, Harbin Institute of Technology, Univeristy Town, Xili, Nanshan, Shenzhen, 518055, China;2. Institute of Industrial Science, The University of Tokyo, Komaba 4-6-1, Meguro-ku, Tokyo, 153-8505, Japan;3. Department of Mechanical Engineering, Faculty of Engineering, Chiba Institute of Technology, Tsudanuma 2-17-1, Narashino, Chiba, 275-0016, Japan
Abstract:NiO/SDC composites and Ni/SDC cermets for solid oxide fuel cell (SOFC) anode applications were prepared from nickel oxide (NiO) and samaria doped ceria (SDC) powders by the powder metallurgy process. The physical and mechanical properties, as well as the microstructure of the NiO/SDC composites and the Ni/SDC cermets were investigated. It is shown that the sintering temperature of the NiO/SDC composites and NiO content plays an important role in determining the microstructure and properties of the NiO/SDC composites, which, in turn, influences the microstructure, electrical conductivity, and mechanical properties of the Ni/SDC cermets. The present study demonstrated that composition and tprocess parameters must be appropriately selected to optimize the microstructure and the properties of NiO/SDC materials for solid oxide fuel cell applications.
Keywords:solid oxide fuel cells (SOFC)  anodes  NiO/SDC composites  Ni/SDC cermets  physical properties  mechanical properties  microstructure
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