| Synthesis and luminescent properties of Eu~(3+)-doped Na_(24)As_2W_(22)O_(83) |
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| 作者姓名： | YANG Shuijin YUAN Liangjie and SUN Jutang |
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| 作者单位： | Yang Shuijin(Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002. China;College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China);YUAN Liangjie,Sun Jutang(College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China) |
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| 基金项目： | This project is financially supported by the National Natural Science Foundation of China (No. 29971024)，the Natural Science Foundation of Hubei Education Committee (No. 2002A00008) |
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| 摘 要： | The Eu3+-doped Na24As2W22O83 phosphor has been prepared by solid state reaction from Na3AsO412H2O, Na2WO4 2H2O and WO3, and characterized by elemental analysis, infrared spectroscopy and powder X-ray diffractometry. According to the measurements with X-ray diffraction, this material belongs to orthorhombic system with its lattice constants: a = 1.4750 nm, b = 1.1944 nm, c = 1.1062 nm, it is consistent with space group D24-P212121 (No.19). The emission and excitation spectra were measured. The luminescent properties of Eu3+-doped Na24As2W22O83 and mechanism of energy transfer were discussed.
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Synthesis and luminescent properties of Eu3+-doped Na24As2W22O83 |
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| YANG Shuijin,YUAN Liangjie,and SUN Jutang
.Synthesis and luminescent properties of Eu~(3+)-doped Na_(24)As_2W_(22)O_(83)[J].Rare Metals,2003,22(2). |
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| Authors: | Yang Shuijin YUAN Liangjie Sun Jutang |
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| Affiliation: | 1. Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002. China;College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
2. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China |
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| Abstract: | The Eu3+-doped Na24As2W22O83 phosphor has been prepared by solid state reaction from Na3AsO412H2O, Na2WO4 2H2O and WO3, and characterized by elemental analysis, infrared spectroscopy and powder X-ray diffractometry. According to the measurements with X-ray diffraction, this material belongs to orthorhombic system with its lattice constants: a = 1.4750 nm, b = 1.1944 nm, c = 1.1062 nm, it is consistent with space group D24-P212121 (No.19). The emission and excitation spectra were measured. The luminescent properties of Eu3+-doped Na24As2W22O83 and mechanism of energy transfer were discussed. |
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| Keywords: | heteropolytungstate europium ion crystal structure synthesis luminescence |
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