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低温等离子体聚合对超细陶瓷粉体的表面改性
引用本文:颜鲁婷,司文捷,苗赫濯,熊韬,何威,郭志刚,蒲以康.低温等离子体聚合对超细陶瓷粉体的表面改性[J].稀有金属材料与工程,2004,33(7):755-758.
作者姓名:颜鲁婷  司文捷  苗赫濯  熊韬  何威  郭志刚  蒲以康
作者单位:1. 北京交通大学,北京,100044
2. 清华大学,北京,100084
基金项目:国家重点基础研究发展规划资助项目(2000067203),北京交通大学“十五”专项科技基金资助
摘    要:利用低温等离子体聚合的方法在超细ZrO2及SiC粉体表面聚合了聚乙烯、聚苯乙烯以及聚甲基丙烯酸甲酯等不同的聚合物层。透射电镜(TEM)、热重(TGA)及漫反射红外光谱的结果表明3nm~8nm厚的聚合物膜存在于超细陶瓷粉体的表面。经低温等离子体聚合处理过的ZrO2粉体在有机载体中的分散性显著提高。液体石蜡体系中,经低温等离子体聚合处理过的ZrO2粉体体系的粘度要远远小于未处理的ZrO2粉体体系。

关 键 词:表面改性  低温等离子体  分散性
文章编号:1002-185X(2004)07-0755-04
修稿时间:2002年12月10

Surface Encapsulation of Ceramic Powders by Low Temperature Plasma Polymerization
Yan Luting,Si Wenjie,Miao Hezhuo,Xiong Tao,He Wei,Guo Zhigang,Pu Yikang.Surface Encapsulation of Ceramic Powders by Low Temperature Plasma Polymerization[J].Rare Metal Materials and Engineering,2004,33(7):755-758.
Authors:Yan Luting  Si Wenjie  Miao Hezhuo  Xiong Tao  He Wei  Guo Zhigang  Pu Yikang
Abstract:In order to prevent the agglomeration and improve the dispersion of ultrafine ceramic powders in liquid paraffin system etc. organic media, different kinds of polymer films were coated on the surface of ultrafine ZrO2 and SiC particles by low temperature plasma polymerization. The encapsulated powders were analyzed by TEM, TGA, and DRIFT. The results show that, the dispersion of plasma treated ZrO2 powders in the organic medium was better than that of untreated ZrO2 powders. The viscosity of liquid paraffin with same solid loading showed a significant difference between plasma treated and untreated ceramic powders.
Keywords:surface modification  plasma polymerization  ceramic powders
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