| 硝酸酯的绿色合成 |
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| 引用本文： | 王庆法,石飞,米镇涛,张香文,王莅.硝酸酯的绿色合成[J].含能材料,2007,15(4):416-420. |
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| 作者姓名： | 王庆法 石飞 米镇涛 张香文 王莅 |
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| 作者单位： | 天津大学化工学院绿色合成与转化教育部重点实验室,天津,300072 |
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| 基金项目： | 国防科工委民口配套“十五”项目(MKPT-2004-32ZD) |
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| 摘 要： | 评述了N2O5为硝化剂制备硝酸酯类含能材料的绿色合成技术,分析了N2O5-有机溶剂硝化、N2O5-固体载体硝化和引入保护基硝化等三种体系工艺的过程和特点,展望了各硝化体系的发展前景。并以N2O5为硝化剂考察了环氧丙烷类化合物开环硝化过程,探讨了取代基的电子效应和立体效应对环氧丙烷类化合物开环硝化过程的影响规律。
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| 关 键 词： | 有机化学 硝酸酯 绿色合成 五氧化二氮 环氧化物 开环硝化 |
| 文章编号： | 1006-9941（2007）04-0416-05 |
| 收稿时间： | 6/4/2007 12:00:00 AM |
| 修稿时间： | 2007-06-042007-07-04 |
Review on Green Synthesis of Nitrate Esters |
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| WANG Qing-f,SHI Fei,MI Zhen-tao,ZHANG Xiang-wen and WANG Li.Review on Green Synthesis of Nitrate Esters[J].Chinese Journal of Energetic Materials,2007,15(4):416-420. |
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| Authors: | WANG Qing-f SHI Fei MI Zhen-tao ZHANG Xiang-wen and WANG Li |
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| Affiliation: | Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology,
Tianjin University, Tianjin 300072, China;Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology,
Tianjin University, Tianjin 300072, China;Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology,
Tianjin University, Tianjin 300072, China;Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology,
Tianjin University, Tianjin 300072, China;Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology,
Tianjin University, Tianjin 300072, China |
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| Abstract: | The green synthesis of nitrate esters using dinitrogen pentoxide (N2O5) as nitrating agent was briefly summarized. Three green nitration systems, N2O5-organic solvent, N2O5-solid support and introduction of blocking group were introduced. The characteristic and prospect of each nitration system were analyzed. The ring-open nitration of propylene oxide compounds was investigated using dinitrogen pentoxide as nitrating agent. The electronic effect and steric effect of substituent on nitration of propylene oxide compounds were discussed. |
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| Keywords: | organic chemistry nitrate esters green synthesis dinitrogen pentoxide epoxides ring-open nitration |
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