| 1,5-二氨基四唑及其系列化合物研究进展 |
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| 引用本文： | 齐书元,张同来,杨利,张建国,臧艳,崔燕.1,5-二氨基四唑及其系列化合物研究进展[J].含能材料,2009,17(4):486-490. |
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| 作者姓名： | 齐书元 张同来 杨利 张建国 臧艳 崔燕 |
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| 作者单位： | 北京理工大学爆炸科学与技术国家重点实验室,北京,100081 |
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| 基金项目： | 国家自然科学基金委-中国工程物理研究院联合基金 |
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| 摘 要： | 介绍了1, 5-二氨基四唑(DAT)的制备方法,重点讨论分析了以二氨基胍盐酸盐为原料制备DAT的优化工艺条件.DAT易与强酸反应形成胺盐、易与高氯酸金属盐形成六个DAT分子直接参与配位的含能配合物,这些化合物具有一定的机械感度和良好的爆炸性能,在含能材料领域具有潜在的应用前景.
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| 关 键 词： | 物理化学 1 5-二氨基四唑(DAT) 制备 配合物 进展 |
| 收稿时间： | 9/2/2008 12:00:00 AM |
| 修稿时间： | 2009/4/22 0:00:00 |
Progress in 1, 5-Diamino-1H-tetrazole and Its Derivatives |
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| QI Shu-yuan,ZHANG Tong-lai,YANG Li,ZHANG Jian-guo,ZANG Yan and CUI Yan.Progress in 1, 5-Diamino-1H-tetrazole and Its Derivatives[J].Chinese Journal of Energetic Materials,2009,17(4):486-490. |
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| Authors: | QI Shu-yuan ZHANG Tong-lai YANG Li ZHANG Jian-guo ZANG Yan and CUI Yan |
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| Affiliation: | State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China;State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China;State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China;State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China;State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China;State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | The progress in the salts and complexes of 1, 5-diamino-1H-tetrazole (DAT) were described and reviewed. The optimized synthesis processes were emphasized with the precursor of diaminoguanidine chloride as raw materials. The DAT can easily forms salt resulting from reacting with strong acid, and easily forms six energetic complexes resulting from coordinating in six DAT molecules with perchlorate. All of these DAT compounds are sensitive to mechanic stimulus,and possess good explosive properties. Therefore, DAT compounds have potential applications in the high energy density materials. |
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| Keywords: | physical chemistry 1 5-diamino-1H-tetrazole(DAT) preparation complex progress |
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