| 相转移法在叠氮粘合剂合成中的应用研究 |
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| 引用本文： | 曹一林,韦伟,靳海波,邓琪玲.相转移法在叠氮粘合剂合成中的应用研究[J].含能材料,2007,15(5):496-499. |
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| 作者姓名： | 曹一林 韦伟 靳海波 邓琪玲 |
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| 作者单位： | 航天科技集团公司四院四十二所,湖北,襄樊,441003 |
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| 摘 要： | 研究了氯化十二烷基苄基三甲基铵和18-冠-6为相转移催化剂时端羟基聚环氧氯丙烷(PECH)在聚环氧乙烷(PEG)和水为介质中的叠氮化反应,探讨了反应规律和反应机理,结果表明:以PECH为介质,十二烷基苄基三甲基氯化铵(TMDA-1)为相转移催化剂的反应体系,可在15 h内使PECH叠氮化转化率达到97%以上,无主链断裂等副反应,是一条较为安全快速的制备叠氮粘合剂的方法。
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| 关 键 词： | 高分子化学 叠氮粘合剂 合成 |
| 文章编号： | 1006-9941（2007）05-0496-04 |
| 收稿时间： | 2006/6/30 0:00:00 |
| 修稿时间： | 2006-06-30 |
Aplication of Phase-transfer Catalysts in the Synthesis of GAP |
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| CAO Yi-lin,WEI wei,JIN Hai-bo and DENG Qi-ling.Aplication of Phase-transfer Catalysts in the Synthesis of GAP[J].Chinese Journal of Energetic Materials,2007,15(5):496-499. |
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| Authors: | CAO Yi-lin WEI wei JIN Hai-bo and DENG Qi-ling |
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| Affiliation: | The 42nd Institute of The Fourth Academy of CASC, Xiangfan 441003, China |
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| Abstract: | With trimethyl,4-dodecylbenezyl ammonium chloride and 18-crown-6 as pase-transfer catalysts,the azidation of polyepichlorohydrin(PECH) in poly(ethylene glycol diol)(PEG) and H2O were studied.The reaction discipline and mechanism were discussed.The results show that the system with trimethyl,4-dodecylbenezyl ammonium chloride as phase transfer catalyst and PEG as medium is a safe and effective approach to glycidyl azide polymer(GAP) preparation,and azidational ratio of PECH can reach 97% above within 15 h. |
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| Keywords: | polymer chemistry azido polyether synthesis |
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