| 高氮含能化合物的合成及反应性 |
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| 引用本文： | 黄明,李洪珍,李金山.高氮含能化合物的合成及反应性[J].含能材料,2006,14(6):457-462. |
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| 作者姓名： | 黄明 李洪珍 李金山 |
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| 作者单位： | 中国工程物理研究院化工材料研究所,四川,绵阳,621900 |
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| 基金项目： | 中国工程物理研究院科学技术基金资助(20050540) |
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| 摘 要： | 综述了四嗪、高氮呋咱和三(四)唑等三类高氮含能化合物(HNECs)的研究现状,叙述了它们的合成方法,介绍了几个典型HNECs的合成路线,提出了合成部分新的HNECs的研究思路。
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| 关 键 词： | 有机化学 高氮含能化合物 合成方法 |
| 文章编号： | 1006-9941（2006）06-0457-06 |
| 收稿时间： | 2006-03-20 |
| 修稿时间： | 2006-07-04 |
Review on Synthesis of High-nitrogen Energetic Compounds |
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| HUANG Ming,LI Hong-zhen and LI Jin-shan.Review on Synthesis of High-nitrogen Energetic Compounds[J].Chinese Journal of Energetic Materials,2006,14(6):457-462. |
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| Authors: | HUANG Ming LI Hong-zhen and LI Jin-shan |
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| Affiliation: | Institute of Chemical Moterials, CA EP, Mianyang 621900, China |
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| Abstract: | High-nitrogen energetic compounds (HNECs) including tetrazines, high-nitrogen furazas and trizoles (or tetrazoles) have characteristics as higher positive heat of formation, better oxygen balance, higher density, and lower sensitivity. The usual synthesis methods of HNECs, and the synthesis route for typical HNECs,including BT, DAAzF and BHT are reviewed. And then some ideas to synthesize new HNECs from non-symmetrical molecular design direction are suggested, i.e. interlinkage between the tetrazine and the farazan, the tetrazine, the pyrazole. |
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| Keywords: | organic chemistry high-nitrogen energetic compounds synthesis methods |
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