含氧富氮含能化合物的合成研究进展

综述了近年来五类含氧(包括硝基氧、羟基氧、配位氧、羰基氧和复合氧)唑基和嗪基富氮含能化合物的合成方法,其中硝基氧富氮含能化合物和复合氧富氮含能化合物的合成研究最为活跃。认为以下几点是今后的研究重点:对合成工艺简单、原料易得的优异含氧富氮含能化合物进行放大合成和实际应用研究;对合成难度大、成本高的优异含氧富氮含能化合物进行工艺改进;设计新型含氧富氮含能化合物时要考虑引进偶氮基和稠环。

Progress of the Synthesis of Nitrogen-rich Energetic Compounds Containing Oxygen

The synthetic methods of five classes of azole-and azine-based nitrogen-rich energetic compounds with oxygen (including nitroxide, hydroxyl oxygen, ligand oxygen, carbonyl oxygen and composite oxygen) in recent years were summarized, in which, studies on the synthesis of nitrogen-rich compounds with nitroxide and composite oxygen are the most active.Considering that the following points are the focus of future research.Studies on the scale-up synthesis and practical application for the excellent nitrogen-rich energetic compounds containing oxygen with simple synthetic process and readily available raw materials are carried out.The process improvement for the excellent nitrogen-rich energetic compounds containing oxygen with high synthesis difficulty and high cost is carried out.When designing a novel nitrogen-rich energetic compound containing oxygen, the introduction of azo group and fused ring should be considered.49 references are attached.