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Enhanced photocatalytic activity of Sr7Mn7O19.62-Dy2O3 nanocomposite synthesized via a green method
Authors:Mahin Baladi  Morteza Hajizadeh-Oghaz  Omid Amiri  Movlud Valian  Masoud Salavati-Niasari
Affiliation:1. Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, P.O. Box 87317-51167, Islamic Republic of Iran;2. Department of Materials Science and Engineering, Esfarayen University of Technology, Esfarayen, North Khorasan, Iran;3. Department of Chemistry, College of Science, University of Raparin, Rania, Kurdistan Region, Iraq;4. Department of Chemistry, College of Science, International University of Erbil, Iran
Abstract:The removal of pollutants existing in industrial wastewater is one of the worldwide main challenging issues owing to the increasing demands for clean water supplies. The purpose of this study is to investigate the feasibility of new synthesized Sr7Mn7O19.62-Dy2O3 nanocomposites for the removal of organic dyes through photo-degradation mechanism from the wastewater. In this regard, for the first time, Sr7Mn7O19.62-Dy2O3 nanocomposites synthesized by the sol-gel combustion method using the different green capping agents and final product characterized via X-ray powder diffraction (XRD), Fourier-transformed infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Energy-dispersive X-ray spectroscopy (EDS), vibrating sample magnetometer (VSM), and Ultraviolet (UV)-visible spectroscopy. Furthermore, the photocatalytic activity Sr7Mn7O19.62-Dy2O3 nanocomposite investigated in the presence of various parameters such as dye type, the effect of pH, and different values of the green capping agents. The results showed that the best photocatalytic activity and hence the removal of pollutants for the proposed nanocomposite (bandgap ?3.25 eV) achieved using Ficus Carica as green capping agent and calcination temperature of 900 °C in the presence of Eriochorme black T dye (photo-degradation of %94.52). This study conclusively shows the potential regarding the development of Sr7Mn7O19.62-Dy2O3 as a novel and effective nanocomposite for wastewater treatment.
Keywords:Ternary oxide  Combustion method  Photocatalytic activity
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