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Effects of magnetic field on water electrolysis using foam electrodes
Affiliation:1. Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan;2. Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, 4-3-11 Takeda, Kofu 400-8511, Japan;1. State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an, 710049, China;2. College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an, 710021, China;1. Laboratory for Advanced Analytical Technologies, Empa - Swiss Federal Laboratories for Material Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland;2. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057, Zürich, Switzerland;3. Laboratory for Magnetic and Functional Thin Films, Empa - Swiss Federal Laboratories for Material Science and Technology, Überlandstrasse 129, 8600, Dübendorf, Switzerland
Abstract:Alkaline water electrolysis using foam electrodes was performed under the influence of a uniform magnetic field. The motivation of doing this work is to combine magnetic field with foam electrode to see if it can get unexpected higher water electrolysis efficiency. The result shows that the energy consumption was reduced by about 3.4% and some unique gas producing properties of foam electrodes were exhibited under the parallel-to-electrode magnetic field. The magnetohydrodynamic (MHD) convection induced by the Lorentz force can accelerate the detachment of bubbles, which are capable to be generated both on the surface and in the interior of foam electrodes simultaneously. Due to the uneven distribution of Lorentz forces, a circulating flow was formed in the electrolyzer, which is special designed to make full use of the circulating flow. The flow scoured the inner space of the foam electrodes so that the void fraction was reduced and the reaction overpotential was decreased. It should be potential to significantly improve the energy efficiency of the hydrogen manufacturing via water electrolysis and provide new ideas for the engineering design of electrolyzer.
Keywords:Water electrolysis  Foam electrode  Magnetic field  Magnetohydrodynamic convection  Electrolysis efficiency
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