Hydrogen storage properties of highly cross-linked polymers derived from chlorinated polypropylene and polyethylenimine |
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| Affiliation: | 1. Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei, 230601, PR China;2. School of Materials Science and Chemical Engineering, Anhui Jianzhu University, Hefei, 230601, PR China;3. Department of Chemical Engineering, Monash University, Clayton, VIC, 3800, Australia;1. College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, People’s Republic of China;2. State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310018, People’s Republic of China;1. Institute for Problems of Materials Science, NAS of Ukraine, 3 Krzhyzhanovsky Str., 03680 Kyiv-142, Ukraine;2. Division ‘Hydrogen and Energy’, EMPA Materials Science and Technology, Überlandstrasse 129, 8600 Dübendorf, Switzerland;1. Department of Physics, Tokyo Gakugei University, Tokyo 184-8501, Japan;2. Institute for Solid State Physics, The University of Tokyo, Chiba 277-8581, Japan;3. National Institute of Advanced Industrial Science and Technology, Ibaraki 305-8565, Japan;4. JST, PRESTO, Saitama 332-0012, Japan;5. Japan Synchrotron Radiation Research Institute, SPring-8, Hyogo 679-5198, Japan;1. School of Materials Science and Engineering and State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;2. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA 16802, USA |
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| Abstract: | Highly cross-linked polymer derived from chlorinated polypropylene (CPP) grafted with polyethylenimine (PEI) was synthesized by hydrothermal amination reaction. The influence of different reaction conditions on the structure and properties of highly cross-linked polymer was investigated. The structures of the polymers named CPP-g-PEI were characterized by Fourier transform infrared (FT-IR) spectroscopy, elemental analysis (EA), 13C solid-state NMR (13C NMR), thermogravimetric analysis (TG), scanning electron microscopy (SEM), transmission electron microscope (TEM), powder X-ray diffraction (PXRD) and nitrogen sorption technique. CPP-g-PEI had honeycomb-like pores with an average size of between 5.37 and 13.54 nm and was thermally stable up to 250 °C. CPP-g-PEI was amorphous porous polymer with some spherulites. The N content of CPP-g-PEI increased and the Cl content of CPP-g-PEI decreased after hydrothermal amination reaction. The hydrogen storage properties of different CPP-g-PEI samples were determined by a hydrogen storage analyzer. Among all samples, hydrogen storage capacity of CPP-g-PEI at 100 °C and triethylamine solvent (CPP-g-PEI-2) achieved the highest hydrogen uptake 11.26 wt% at 77 K, 5 MPa. In addition, OH? type CPP-g-PEI (CPP-g-PEIOH?) exhibited a hydrogen uptake of 2.47 wt% at 300 K, 5 MPa. BET specific surface area of the sample was not directly associated with hydrogen storage capacity. Hydrogen adsorption enthalpy of CPP-g-PEI-2 was calculated by the Arrhenius equation to be 38.79 kJ/mol and the adsorption process of CPP-g-PEI was investigated to be reversible physical adsorption. |
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| Keywords: | Chlorinated polypropylene graft polyethylenimine Cross-linked polymers Porous polymers Amination Hydrogen storage |
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